冰及HCFC-141b气体水合物蓄冷性能研究

在一台可视化蓄冷槽(容积为O.16m^3)的蓄冷实验系统上进行了冰和HCFC一141b水合物蓄冷实验研究．结果表明：HCFC-141b水合物主要在盘管的问隙中生长，具有非贴壁生长现象；在实验条件下冰的蓄冷量为HCFC-141b水合物蓄冷量的1．59～2．10倍。但HCFC-141b水合物蓄冷速率达6666.7kJ／h。是冰蓄冷速率的1.62倍．表面活性剂SDS对增加水合物蓄冷量的作用明显，比没有添加SDS时水合物蓄冷量增加约32％。同时对蓄冷速率也有提高．     

二氧化碳压力对甲烷水合物置换速率的影响

通过检测置换过程中气相组分的变化情况,研究了CO2注入压力对置换CH4水合物中CH4气体程度与速率的影响.在274.15 K时,研究了3.97,4.56,4.84,6.26M Pa 4个不同的CO2注入压力下置换反应的进行情况.实验表明,当置换反应结束时,分别有20.0%,26.4%,44.9%,9.1%的CH4被置换出来.在一定压力范围内(3.97~4.84 M Pa),CO2气体注入压力越高,被置换出来的CH4量越大,但当CO2气体注入压力接近液化压力时,CH4回收量反而明显下降.     

Experimental Study of Natural Gas Storage in Hydrates

Hydrate formation rate plays an important role in the making of hydrates for natural gas storage. The effect of sodium dodecyl sulfate (SDS), alkyl polysaccharide glycoside (APG) and cyclopentane (CP) on natural gas hydrate formation rate, induction time and storage capacity was studied. Micellar surfactant solutions were found to increase hydrate formation rate in a quiescent system and improve hydrate formation rate and natural gas storage capacity. The process of hydrate formation includes two stages with surfactant presence. Hydrate forms quickly in the first stage, and then the formation rate is slowed down. Surfactants (SDS or APG) reduce the induction time of hydrate formation. The effect of an anionic surfactant (SDS) on gas storage in hydrates is more pronounced compared to a nonionic surfactant (APG). CP also reduces the induction time of hydrate formation, but can not improve the natural gas storage capacity in hydrates.