养生作用对硫沥青性能影响分析

硫磺部分替代传统石油沥青用于道路工程建设可减少石油沥青用量,降低施工能源消耗,促进工业废渣中硫磺的回收利用,具有较高的经济和环保价值。为探究硫磺掺量（质量分数）及养生作用对硫沥青（SEA）性能的影响,采用差示扫描量热仪（DSC）验证硫沥青中硫磺的重结晶现象,对养生前后硫沥青的基本物理性能和黏度进行分析,并采用动态剪切流变仪（DSR）和弯曲梁流变仪（BBR）对养生前后硫沥青的流变特性和疲劳性能进行评价,最后借助荧光显微镜（FM）观察养生前、后硫磺在沥青中的微观分布特性。研究结果表明：养生后高硫磺掺量的硫沥青DSC曲线出现吸热峰,硫沥青（特别是高硫磺掺量下）的劲度有所增加,因此对硫沥青进行养生使其性能稳定后再进行相关性能评价更具现实意义;硫磺掺量较低（≤ 10%）时,硫磺主要以溶解硫的形式存在于沥青中起到软化沥青的作用,因此沥青的低温变形能力有所改善,但其高温抗变形能力有所降低;当硫磺掺量较高（≥ 35%）时,硫磺主要以重结晶的形式悬浮在沥青中使沥青变硬,在增加沥青高温抗变形能力的同时也牺牲了其低温抗裂能力;硫磺掺量较低时,硫沥青黏度随着硫磺掺量的增加而降低;硫磺掺量较高时,硫沥青90℃和105℃黏度随着硫磺掺量的增加而增加,但硫沥青120℃和135℃黏度相差不大,同时硫磺加入最高可降低沥青的施工温度达20℃;线性振幅扫描（LAS）试验结果表明,养生后的硫沥青疲劳寿命比基质沥青长,其中35%硫沥青疲劳性能最佳;硫磺掺量进一步增加,硫沥青疲劳寿命缩短至与基质沥青相近;FM分析表明,硫磺掺量不高于5%时,硫磺全部溶解于沥青中,且养生后硫磺未重结晶,相应硫沥青无荧光性;硫磺掺量高于5%时,硫磺在沥青中分布均匀,养生后10%硫沥青中硫晶斑尺寸和面积显著增大,高硫磺掺量硫沥青中硫晶斑面积仅略有增加。     

船舶低硫柴油系统设计的分析与优化

就新辟航线首制船“汉亚直达”集装箱船的低硫柴油系统,叙述了船舶低硫柴油系统的设计经验,从当前国内外对船用燃油硫含量的要求、应对方案到船舶低硫柴油冷却方式选择、低硫柴油冷却系统设计、高/低硫柴油转换、使用低硫柴油风险分析及处理等方面进行详细叙述,为业内同行提供参考。     

2020全球限硫令对海员权益的影响

2020全球限硫令的推出,对各方均造成了极大的影响。为确保海员权益不受损害,文章结合国内外资料以及对部分海员的访谈,在国内首次系统分析了2020全球限硫令的实施对海员在人身安全、职业健康、工作休息、工资报酬、责任追究等五方面影响;并首次从船东和主管机关的角度分别提出了履行2020全球限硫令时保护海员权益的建议,即船东要加强培训、确保船舶配员、关注海员职业健康和工资报酬,船旗国和港口国主管机关要加强海员权益保护检查、确保提供合格燃料油以及给予海员足够的宽容和理解等。     

液态硫磺运输船热煤油加热系统及罐体保温研究

针对液态硫磺的物理特性及运输条件,使用热煤油加热系统对液态硫磺进行保温、加热.对液态硫磺船加热系统中的硫磺罐保温层、热煤油加热系统做了分析,提出硫磺热煤油加热系统的可行性设计方法、经济保温层的计算公式,阐述了硫磺罐加热盘管设计应注意的问题.     

硫含量对柴油车排放的影响与减排措施的研究

分析硫含量对柴油车排放物PM、NOx、CO的影响,并通过分析硫含量对氧化催化转化(DOC)、柴油颗粒过滤(DPF)、NOx排放控制等排气后处理技术的影响,提出相应的有效减排措施。     

船舶低硫燃油系统的应用分析

介绍低硫燃油的特性及其关键技术,分析低硫燃油市场供应情况,结合工程应用实际,提出了4种应用方案,经过对比分析,提出了一种面向工程实际的推荐方案。     

铁水含硅量实时预报专家系统的设计与实现

将时差方法与人工神经元网络方法有机地结合起来,提出了一种在高炉铁水含硫量预报中的应用策略。并基于鞍钢10#高炉操作过程,建立了高炉铁水含硫量预报专家系统。     

一种船用低硫油冷却系统电气控制设计

根据国际公约对燃油含硫量的要求,设计了一种低硫油冷却系统,介绍其组成并具体地分析了电气原理图。此系统已应用于生产实际,性能达到预期效果,有一定的参考价值。     

重型柴油机达国IV SCR试验研究

为满足不断加严的柴油机排放限值要求,采用SCR技术降低NOx排放水平满足国IV要求。通过对SCR温度、空速特性的研究,提出尿素喷射稳态控制、瞬态修正策略,并通过1000h耐硫老化性试验,验证SCR技术是适合我国国情的排放解决方案。     

Biogeochemistry of sulfur in a sediment core from the west-central Baltic Sea: Evidence from stable isotopes and pyrite textures

The biogeochemistry of the sulfur cycle in a ca. 5-m-long sediment core from the eastern slope (221 m water depth) of the Landsort Deep in the west-central Baltic Sea was investigated by analyzing the solid phase records of sulfur isotopes and pyrite textures, besides selected main and minor elements. The sediments were deposited during post-glacial history of the Baltic Sea when the basin experienced alteration of brackish (Yoldia Sea, Littorina Sea) and freshwater (Baltic Ice Lake, Ancylus Lake) conditions. The stable isotopic composition of total sulfur was analyzed as a function of depth. In selected samples pyrite (FeS₂), greigite (Fe₃S₄), and barite (BaSO₄) fractions were separated for isotope analyses. Pyrite textures were analyzed by SEM and optical microscopy.Microbial reactions associated with the oxidation of organic matter resulted in assemblages of authigenic sulfide minerals which for the post-Ancylus Lake brackish water environment are dominated by pyrite and for freshwater environments by Fe-monosulfides. The sulfur isotopic composition of the brackish water Littorina Sea sediments (δ³⁴S between −40 and −27‰ vs. V-CDT) is believed to be determined by cellular sulfate reduction rates and reactions involving intermediate sulfur species. The availability of reactive iron and decomposable organic matter as well as sedimentation rate and the chemocline position are important variables upon the δ³⁴S values of sulfides in brackish water environment. The syn-depositional abundance of sulfur and organic matter, and transport of dissolved sulfur species vs. rates of microbial reactions determine δ³⁴S in the freshwater sediments. The upper part of the Ancylus Lake sediments is sulfidized by downward diffusing H₂S and/or sulfate from overlying brackish water sediments. Minor concretionary barite formation in the freshwater sediments is most likely due to the reaction of pore water sulfate diffusing downward from brackish water sediments with barium desorbed from freshwater sediments. The size distribution of pyrite framboids in the brackish sediments indicates that the formation mainly occurred from anoxic pore waters, although some pyrite formation in an anoxic water column cannot be excluded.