非晶态合金催化剂在催化中的应用

非晶态合金是一种新型催化剂.重点介绍了非晶态合金用作催化剂材料在电催化反应、加氢反应和脱氢反应以及氨合成反应等中的应用及对非晶态合金用作催化剂材料的发展前景作了评述.     

Experimental and finite element analysis of fatigue strength for 300 mm2 copper power conductor

The fatigue strength of a 300 mm² stranded copper conductor was investigated experimentally and by finite element (FE) analysis. An analytical model was also developed and validated. Wires taken from the outer layer of the conductor were fatigue tested in tension–tension loading and compared with similar data for wires taken from a 95 mm² conductor. The wire cross section was deformed due to the compacting process that was applied during fabrication. When corrected for stress concentrations due to the deformation the data for the two sets of wire fell within the same scatter-band. Full scale testing was carried out in a specially designed rig with constant tensile load and reversed displacement controlled bending with a fixed curvature variation. The loading is a simulation of the loading of a power cable hanging from a floating vessel through a bellmouth. Conductors were tested in two states; dry and lubricated. A finite element model was established for the copper conductor. The model was formulated by a combination of elastic beam and beam-contact elements that included the effects of friction. The effect of local bending due to contact forces was included in the model. Two contact conditions were investigated; the point (trellis) contact between adjacent layers of wire and the inline contact within each layer and between the first layer (centre wire) and the second layer. The FE model was validated by a calibration test of a full scale conductor, and by sensitivity studies varying the size and the number of elements of the model. Fatigue analysis of the conductor was carried out, based on the S–N curve for individual wires. Taking into account the effects of friction and local bending, agreement was obtained between predicted and experimental fatigue strength of the conductor, for the FE model as well as the analytical model.     

Fe—21Ni—4Mn合金磁场诱发马氏体形貌和惯习面

本文采用强脉冲磁场、光学显微镜和 H.R.Pak 等提出的惯习面确定方法研究了 Fc-21Ni-4Mn 合金中磁场诱发马氏体形貌和惯习面.结果表明,Fe-21Nj-4Mn 合金冷却形成板条马氏体,而在 Ms 温度以上,磁场诱发形成多片状而少板条马氏体,且随温度升高,磁场诱发马氏体形貌为蝶状.磁场诱发马氏体惯习面与冷却形成的马氏体相同,均为(225),对于蝶状马氏体发现了一种新的对称面(110).     

Fe—Mo合金的时效析出行为

用 X 射线、电子衍射及透射电镜观察等方法研究了 Fe-27Mo 及 Fe-16Mo 合金的时效析出行为.结果发现,在873～1453K 时效时.时效初期,两种合金中均有一种新的过渡相——R 相析出.随时效进行,过渡相 R 将向平衡相μ(1213～1453K)或 Laves(873～1213K)转度.过渡相 R 为菱形点阵,点阵常数α=0.8977nm,α=74.4°,其 Mo 含量为48%,呈棒状或块状形态析出.时效初期由于过渡相 R 的析出引起合金硬化.     

Ni-P,SiC化学复合镀层耐磨性的研究

本文介绍了获得非晶态Ni-P,SiC化学复合镀层的试验方法,研究了复合镀层在晶化条理过程中,显微硬度及磨损量的变化情况,得到了硬度高、耐磨性好的晶化处理条件,同时还研究了SiC粒径及共析量对复合镀层磨损量的影响,并对镀层的微结构进行了分析。     

钛合金的研究进展与应用现状

综述了国内外钛合金的研究进展和应用现状,具体介绍了航空用钛合金、船用钛合金及低成本钛合金的研究进展,简要概述了钛合金在航空航天、舰船及汽车和化工行业的应用现状,并对我国钛行业的发展进行了展望。     

新型锌铝合金在阀门生产中的应用

在分析阀杆螺母服役条件的基础上，对用价格低廉的锌铝合金生产阀杆螺母进行了成分设计，确定了新型的锌铝合金－ZA33－3，并对其了力学性能及耐磨性能试验，结果表明，新型ZA33－3合金的各项性能指标全面超过铜合金，是替代铜合金生产阈杆螺母的理想材料，而其价格仅为铜合金的1／3。     

金属纤维增强铝合金复合材料界面相互作用规律的研究

本文研究了金属纤维增强铝合金复合材料中纤维同基体间的界面相互作用规律.试验结果表明,金属纤维同液相铝合金基体的作用温度愈高,作用时间愈长,则界面内层(扩散层)的柱状晶Fe_2Al_5愈发达,含有以颗粒、团块、层状形态存在的FeAl_3(Sn)金属间化合物的界面外层(凝固层)将逐渐减薄或消失;固相加热保温时,界面内层Fe_2Al_5生长规律为X=X_0+2.0559×10~6·exp(-6.378×10~4/RT·t~(12)(μm).     

AS-X树脂的增韧及耐候性研究

用马来酸酐MAH熔融接枝POE制得POE-g-MAH,用其作为AS与POE的相容剂,提高AS树脂韧性与耐候性,并研究了PE-g-MAH和PP-g-MAH作为相容剂PC/AS共混物的增韧作用.用摆锤式冲击试验机、拉伸试验机测试增韧效果,用SEM,FTIR,DSC等测试手段研究产物及共混物的共组成、相容性、相结构、热稳定性.结果表明：PC/AS共混物增韧效果比POE-g-MAH/AS好,PC/AS共混物缺口冲击强度达到5.45 J/m2几乎是纯AS树脂（1.2 kJ/m2）的5倍.     

焊接工艺对6061-T6铝合金接头疲劳性能的影响

通过脉动拉伸疲劳性能试验和对疲劳断口的形貌分析,分别对不同线能量、不同预热温度和不同层间温度下的6061-T6铝合金MIG焊对接接头疲劳性能进行了研究.结果表明:随着线能量的增加和预热温度的降低,接头指定寿命为1×107的中值疲劳极限σ01有所升高,且在不同层间温度下,层间温度为70 ～90℃时中值疲劳极限σ01较高.疲劳试验中所有断裂试件均在焊缝处断裂,其断口形貌分析表明:试验试件焊缝处表面或近表面的气孔是整个疲劳断裂的启裂源,在脉动载荷的作用下,裂纹从此处产生并向内部逐渐扩展.疲劳裂纹启裂区和扩展区具有典型的疲劳断裂特征,疲劳纹清晰,终断区为韧窝型断口形貌.