ZX—01镍磷合金化学镀工艺研究及应用

结合重型汽车典型令中件的特点，研究开发了一种性能优良的镍磷合金度工艺，采用正交试验法研究了镀液主要组分及主要工艺参数对镀层性能的影响规律，并对络合剂、缓冲剂和稳定剂进行了对比和筛选，优化最佳配方和工艺。该工艺操作简单，镀层综合性能优良，镀液稳定性好，寿命长，实际应用表明，ZX－01镍磷合金化学镀工艺完全可以用于生产，取代原来的电镀锌、电镀铬工艺。     

Influence of the heavy fuel spill from the Prestige tanker wreckage in the overlying seawater column levels of copper, nickel and vanadium (NE Atlantic ocean)

The water column above the Prestige wreckage was sampled during two consecutive campaigns: Prestinaut (December 2002) two weeks after the tanker sunk and HidroPrestige0303 (March 2003) one month after the sealing of the main fuel leaks. Samples of the original cargo fuel and the emulsified fuel in the surface of the ocean were also collected. Analysis of the fuel indicated the release of 135 kg of Cu, 1700 kg of Ni and 5300 kg of V from the original fuel to the water column, remaining 35 kg of Cu, 3100 kg of Ni and 13,800 kg of V in the emulsified fuel. The metal partitioning between the water column and the emulsioned floating fuel, Cu > Ni ~ V, are in accordance with the stability index for the metal–nitrogen bond in metalloporphyrins. This release had an impact on dissolved trace metal concentrations in the water column. An increase on dissolved copper (2.8–4.7 nM) and nickel (2.2–8.0 nM) with respect to natural values (1–3 nM for Cu and 1.6–5 nM for Ni) was observed. Values for vanadium (28–35 nM) were in the range of pristine North Atlantic waters (30–36 nM). This contamination was especially observed in the upper water column (0–50 m), associated with the mixing of seawater with the fuel moving upwards, and in deep waters, where the residence time of fuel is higher. Future research in this field should focus on the environmental variables and the processes that control the release of contaminants from fuels for a better assessment of the contamination in oil-spill events.     

氨基磺酸镍合成工艺的研究

简要回顾了氨基磺酸镍传统的合成工艺;从提高质量和产量方面考虑,系统研究了一种合成氨基磺酸镍的新工艺,即先采用氨配合沉淀法制备出球形氢氧化镍,再加入氨基磺酸合成氨基磺酸镍;讨论了反应温度、反应体系的pH值、搅拌强度、镍氨比对氢氧化镍浓度的影响。结果表明:运用该工艺合成的氨基磺酸镍杂质含量低,质量稳定。     

A numerical study of the effects of the longitudinal baffle on nickel ore slurry sloshing in a prismatic cargo hold

The nickel ore slurry sloshing in a rolling partially loaded prismatic cargo hold with a longitudinal baffle is investigated. A numerical model based on the volume of fluid (VOF) method and the non-Newtonian Herschel-Bulkley and Bingham equations is proposed to study the dynamic behavior of nickel ore slurry sloshing. The numerical model is solved by using the finite volume approximations and the dynamic mesh technique is utilized to handle the cargo hold's motion. After taking grid and time step independence study, the numerical results are compared with experimental data. Comparisons show good agreement in the cases investigated. Further, the relationship between the moment amplitude induced on the hold boundary and the excitation frequency is checked numerically. The ratio of baffle height to the initial cargo depth has been changed in the range of 0.0 ≤ h_B/d ≤ 1.2. The variation of the sloshing-induced moment and the deformation of the free surface under different baffle heights have been obtained and discussed. To clearly understand the sloshing behavior of nickel ore slurry, the sloshing of liquid water has also been carried out. Meanwhile, the dynamic viscosity of the nickel ore slurry is monitored. The critical baffle height with regard to the sloshing-induced moment and the elevation difference of the free surface at two sides of the cargo hold has also been presented and discussed.     

浅谈铝合金轮毂电镀镍前的预处理

铝合金电镀只要做好前处理,基本上就不会产生起泡、掉皮等质量缺陷,尤其是关键工序的生产,要想提高电镀一次合格率,铝轮毂前处理质量的好坏是铝轮毂电镀最重要的因素。     

汽车行业涂装车间排放废水中的镍离子去除方法概论

针对汽车主机厂涂装车间产生的磷化废水,采用化学沉降法去除废水中的镍离子。分别进行了pH值、凝聚剂、絮凝剂投加量以及沉降时间(系统停留时间)对镍离子去除效果影响的试验。结果表明,最佳工艺条件为pH>10.5,沉降时间>4 min,在足够的凝聚剂和适宜的絮凝剂投加量的条件下,废水中镍离子去除率在99.0%以上。将最佳工艺条件应用于工程实际中,废水处理后,出水的镍离子浓度可控制在0.05 mg/L以下,远低于1 mg/L,满足了GB 8978—1996《污水综合排放标准》中镍的排放标准。