Preparation and Characterization of a Novel Hybrid Copolymer Hydrogel with Poly（ethylene glycol） Dimethacrylate, 2-Hydroxyethyl Methacrylate and Layered Double Hydroxides

This paper describes the fabrication, characterization and properties of a novel hybrid poly(ethylene glycol) (PEG) based hydrogel via in situ polymerization. The hybrid hydrogel was fabricated by free-radical redox polymerization using ammonium persulfate (APS) and N, N, N??, N??-tetramethylethylenediamine (TEMED) as initiators and N, N??-methylene bisacrylamide (BIS) as cross-linker at 60°C. To create a hybrid hydrogel, 0.2% (mass fraction) of MgAl layered double hydroxide (LDH) was added to the aqueous solution by ultrasonic dispersion. The physicochemical properties of hybrid hydrogel under vacuum freeze-drying processing were characterized by Fourier transform infrared (FTIR) spectroscopy, thermal gravimetric analysis (TGA) and scanning electron microscopy (SEM), while swelling kinetics and gel content were calculated. Swelling degree in distilled water varied from 94%?C125% with a gel mass fraction of 83%?C91%. SEM images showed that the micron pore size of hydrogel could be adjusted within the range of several micrometers by changing the cross-linker mass fraction from 2% to 10% (based on glycol). The results showed that the hybrid hydrogels exhibited excellent physicochemical behavior and might be a promising material for applications in tissue engineering and drug delivery.     

绿色生物防污剂及控制释放技术研究进展

基于传统防污剂的毒性危害和释放不稳定性问题,聚焦于绿色生物防污剂和防污剂缓控释放技术,总结天然生物防污剂和人工合成防污剂近年来的相关研究进展。微纳米管控释技术、微胶囊包覆技术和温敏水凝胶控释技术在控释方面具有显著优势,综述其最新进展,并给出未来开发绿色防污剂和新型防污剂控释技术方面的相关建议。