一种改进的Ni—PTFE化学复合镀工艺

针对传统Ni—PTFE化学复合镀工艺的规律和不足,经过对试剂和工艺参数的筛选,改进配方和工艺条件,提出了一种经过改进的Ni—PTFE化学复合镀工艺,获得了在厚度、力学性能和稳定性方面均有较大提高的化学复合镀层。     

化学复合镀及其应用

化学复合镀是一种新型表面处理技术。探讨了复合镀的机理及其应用 ,主要包括耐磨复合镀层 ,如Ni -P -SiC复合镀等 ,还有自润滑复合镀层 ,如Ni -P -PTFE复合化学镀层等。最后对化学复合镀在机车车辆制造业方面的应用作了展望。     

化学镀镍产品在电力机车上的应用

由于电力机车电镀产品存在镀层不均匀、表面状况差、无装饰性以及镀层硬度低、不耐磨擦等缺陷,文章介绍的化学镀镍工艺以其优越的工艺性能很好地解决了以上工艺问题。     

INFLUENCE OF SURFACE MORPHOLOGY ON THE MICROHARDNESS OF ELECTROLESS Ni-B DEPOSIT REVEALED BY AFM OBSERVATION

Introduction　　 Electroless Ni- B alloy has many advantagessuch as superior hardness,excellent wear- resis-tance and some special electrical and magneticproperties[1,2 ] . It can be prepared with eitherDimethylamineborane( DMAB) or sodium borohy-dride as reductant[3 ,4] .The deposits with lowerboron contentwhich are mainly applied to electron-ic industry[5] are prepared by DMAB.While sodi-um borohydride can bring about higher boron con-tent deposits which are chiefly used as wear- resis-…     

AZ91D镁合金直接化学镀镍工艺的研究

为解决镁合金传统化学镀镍方法工艺复杂、不适用于铝含量较高的镁合金以及使用氰化物、废液需处理等问题，研究了在AZ91D镁合金表面直接化学镀镍的工艺。介绍了工艺流程、溶液成分和工艺参数，用SEM观察了镀层与基体的结合情况、镀层表面形貌，并测试了镀层的硬度、结合力和耐腐蚀性能。结果表明，所得镀层平整、光亮、致密，与基体结合牢固，可有效保护镁合金免遭腐蚀。     

INFLUENCE OF SURFACE MORPHOLOGY ON THE MICROHARDNESS OF ELECTROLEESS NI-B DEPOSIT REVEALED BY AFM OBSERVATION

A crystalline and non-crystalline two-phase Ni-B coating was prepared by electroless deposition with potassium borohydride as reducing agent. When the deposit was heated from 10 C to 500 C, it took place three kinds of phase transformation and formed corresponding nickel borides. An Atomic Force Microscopy (AFM) was used to directly view the surface morphologies of the samples in various treated states. The AFM images indicate that nano-dimensional protrusions grow on the surface of the deposit grain during some heat treatment processes,and they are distinguished greatly from the small bulges existing in the as-plated deposit. Further studies show that the microhardness related to the surface topography of thecoating to some extent. Especially when a two-step heat treatment process was performed, the nano-dimensional protrusions on the grain surface grew upt to 40～100nm in diameter and 10～20 nm in height, and the deposit microhardness reached up to HV1500～ 1600 in the meantime.     

货车脱轨自动制动阀可靠性的探讨及建议

根据脱轨制动阀的作用原理，结合生产中遇到的情况，探讨影响运用可靠性方面的问题，并提出一些建议。     

AZ91D化学镀Ni-P结合强度研究

利用金相显微镜、SEM、能谱仪(EDS),研究了镁合金AZ91D的化学镀Ni-P的结合强度。结果表明,镁合金基体的镀前处理对镀层的结合强度至关重要。没有经过前处理的镁合金的镀层结合力差,而经过严格前处理的镀层结合力良好。前处理中酸洗、活化以及在对镁合金基体打磨过程中残留的杂质对镀层结合强度的影响较大,特别是Fe、C等杂质元素的掺入使得镀层的结合强度大大降低;pH值也对镀层的结合强度有很大影响,随着pH值的升高,镀层的结合强度降低。     

冲击划痕法测定Ni—P化学镀层结合强度

介绍了一种评价镀层结合强度的新方法－单摆冲击划痕法。它能有效地评价和定量地测定镀层与基材的结合强度以及冲击截荷下镀层的耐磨性能。用冲击划痕法测定Ｎｉ－Ｐ化学镀层与碳钢结构强度的试验结果表明，保持合适的基材表面粗糙度，控制基材的含碳量以及选择适当的热处理温度可以提高Ｎｉ－Ｐ化学镀层与基材的结合强度承载能力。     

微弧氧化陶瓷表面无钯活化化学镀铜的研究

用氢氟酸活化方法取代传统的钯胶活化法,在镁合金微弧氧化陶瓷膜表面经化学镀铜制备了陶瓷／铜协合膜层。结果表明,铜层连续均匀地覆盖微弧氧化陶瓷层表面,渗入并填充陶瓷层内部呈网状分布的孔隙,实现了铜层与陶瓷层在呈网络状分布的孔隙处产生机械咬合、钉扎或锁扣。以价健理论分析了材料表面析氢电催化活性过程,探讨了微弧氧化陶瓷层表面氢氟酸活化机理。