Sources and exposure risk of trace elements for traffic policemen in roadside locations

Samples of PM_2.5 and PM₁₀ at four types of roadside location (major road, secondary road, branch road, and expressway) in Tianjin were collected and analyzed in 2015. The average annual roadside PM_2.5 and PM₁₀ concentrations were higher than the national ambient air quality standard (NAAQS: GB3095-2012). The chromium (Cr), manganese (Mn), nickel (Ni), zinc (Zn), arsenic (As), and cadmium (Cd) concentrations in both PM_2.5 and PM₁₀ over four seasons displayed significant differences (p < 0.05). An enrichment factor (EF) analysis revealed that Cd, copper (Cu), Zn, As, Ni, and Pb in PM_2.5 and PM₁₀ mainly originated from anthropogenic sources. A factor analysis (FA) and correlation analysis (CA) revealed that vehicle emissions (exhaust and non-exhaust), soil dust, coal combustion, and industrial emissions were the main sources of roadside PM_2.5 and PM₁₀ in Tianjin. Both the total hazard quotients (total HQ) and the total carcinogenic risk (total CR) for selected elements in PM_2.5 and PM₁₀ were within acceptable limits. The HQ of Pb was higher than for other metals, and it should therefore be given special attention. The CR for traffic policemen was highest for Cr exposure (1.01 × 10⁻⁵ for PM_2.5 and 1.52 × 10⁻⁵ for PM₁₀), followed by As and Ni. A sensitivity analysis showed that the total contributions of the metal concentrations, exposure time (ET), and exposure frequency (EF) accounted for over 50% of the risk for Cr, As, and Ni, suggesting that these metals had the greatest impact on the uncertainty of health risk assessments.