| Diels-Alder反应的理论研究新进展 |
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| 引用本文： | 徐文媛,杜瑞焕,龙威.Diels-Alder反应的理论研究新进展[J].华东交通大学学报,2011,28(3):60-64. |
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| 作者姓名： | 徐文媛 杜瑞焕 龙威 |
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| 作者单位： | 华东交通大学基础科学学院,江西南昌,330013 |
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| 基金项目： | 国家自然科学基金项目，江西省自然科学基金项目，华东交通大学研究生创新基金项目 |
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| 摘 要： | Diels-Alder反应已经成为合成六元环加成化合物、天然萜类化合物和药物中间体、哌啶衍生物的一个关键步骤,随着在合成领域取得令人瞩目的成果,Diels-Alder反应的机理研究也取得了一定的进展.该文综述了国内外Diels-Alder反应最新的理论研究,在催化剂lewis酸、噁唑硼烷、水溶剂、离子溶剂和超临界CO2...
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| 关 键 词： | Diels-Alder B3LYP/6-311G 噁唑硼烷 离子液体 水 超临界CO2流体 |
Progress of the Theory Study on Diels-Alder Reactions |
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| Xu Wenyuan,Du Ruihuan,Long Wei.Progress of the Theory Study on Diels-Alder Reactions[J].Journal of East China Jiaotong University,2011,28(3):60-64. |
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| Authors: | Xu Wenyuan Du Ruihuan Long Wei |
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| Institution: | (School of Basic Sciences,East China Jiaotong University,Nanchang 330013,China) |
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| Abstract: | Diels-Alder reaction is used as a key step in synthese of six-membered cycles,terpene natural products,drug intermediates,piperidine derivatives.With the distinct achievements on the synthesis,some theoretical progresses of Diels-Alder reactions are accomplished.This paper reviews the latest theoretical researches of Diels-Alder reaction at home and abroad.Based on the theory of quantum chemistry,the effect of the catalysts（such as AlCl3 or oxazaborolidines） and solvents（such as water,ionic liquids and supercritical-CO2 fluid） are discussed.Those influences on the rate and highly stereoselective of reaction are investigated in detail.In addition,the theoretical future in Diels-Alder Reactions is forecasted,which adapts to the development of Green Chemistry. |
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| Keywords: | Diels-Alder B3LYP/6-311G oxazaborolidines ionic liquids water supercritical-CO2 fluid |
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