矿粉-粉煤灰-石灰石粉胶凝体系耐低温硫酸盐腐蚀研究

该文设计了从净浆、砂浆到混凝土一系列的矿粉-粉煤灰-石灰石粉-硅酸盐水泥胶凝体系在冰点以上的低温、硫酸镁溶液环境下的受侵蚀过程。净浆浸泡研究结果表明:在无粉煤灰掺入情况下,石灰石硅酸盐水泥受硫酸盐低温侵蚀的程度与石灰石粉在水泥中的比例有关,且呈正比关系,即石灰石粉含量愈高,受侵蚀程度愈严重;对受侵净浆剥离物的XRD分析结果证实石灰石硅酸盐水泥受侵是由于CaCO3与氢氧化钙、水化硅酸钙和硫酸镁反应生成了类似水化硫铝酸钙的产物(称其为水化碳硫硅酸钙)有关。当有矿粉、粉煤灰介入该体系后,可以明显改善石灰石硅酸盐水泥耐硫酸盐低温侵蚀性能。砂浆浸泡试验结果表明:当矿粉、粉煤灰替代石灰石粉达50%(总量达水泥胶凝体系质量的30%)时,胶砂强度损失由无粉煤灰替代的3个月8.8%、6个月13.4%,分别下降至3个月1.5%、6个月2.8%。混凝土试验结果与胶砂和净浆浸泡结果是一致的:单掺石灰石粉的混凝土低温浸泡6个月后外观已经出现明显的裂纹,浸泡后强度损失超过20%;当矿粉、粉煤灰以50%替代石灰石粉时,强度损失下降至8.0%。

Study on Lowe-temperature Resistance Sulfate Corrosion of Mineral Powder-Fly Ash-Limestone Powder Gelling System

The article designs the weathering process of mineral powder-fly ash-lime powder Portland cement gelling system from the a series of slurry,mortar and concrete under the circumstance of low temperature over freezing point and bitter salt solution.The slurry marinating result makes clear that the weathering extent of limestone Portland cement by sulfate and low temperature is related with the proportion of limestone powder in the cement,and presents the direct ratio relation,i.e.the higher the limestone powd...