Air pollution impact of maritime shipping operations in the port of Houston

Abstract

Major air pollutants from maritime shipping operations are sulfur oxides, nitrogen oxides, and particulate matter emissions from combustion of fuel oil during cruise, berth, and start‐up modes. Sulfur oxides emissions are substantial from steamships burning high‐sulfur residual fuel oil, where shipping contributes 66 percent of the total sulfur dioxide emissions from transportation sources, and almost 3 percent of the total for Harris county, Texas. Nitrogen oxides emissions are significant during cruise conditions for both steamships and motor ships, while particulate emissions are substantial during start‐up and tube cleaning.

Significant marine air pollutant emission sources are found in busy harbor areas such as the Houston Ship Channel. Offshore terminals for unloading large tankers may result in emissions of 10 to 20 tons of sulfur oxides daily per ship, and 3 to 5 tons of nitrogen oxides daily per ship during pumping operations. Trace‐metal constituents present in the oil may catalyze sulfur dioxide and nitrogen dioxide oxidation to their respective sulfate and nitrate aerosols in the humid Texas Gulf Coast atmospheres to aggravate photochemical air pollution problems once the air masses reach industrial and populated urban areas on land. Onshore sulfur dioxide and particulate‐matter emission controls may be necessary for some large ships in port to minimize potential impact on coastal zone air quality.