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Na_3La_9B_8O_(27):Ln~(3+)(Ln=Eu或Tb)荧光体的制备与发光性能
引用本文:张鲁宁,李志华.Na_3La_9B_8O_(27):Ln~(3+)(Ln=Eu或Tb)荧光体的制备与发光性能[J].华东交通大学学报,2008,25(4):80-84.
作者姓名:张鲁宁  李志华
作者单位:山东师范大学,化学化512与材料科学学院,山东,济南,250014
摘    要:采用高温固相合成技术、溶胶-凝胶法、助熔剂法制备了Na3La9B8O27:Ln^3+(Ln=Eu或Tb)荧光体,确定了固相反应制备该荧光体适宜的组分re.g,j.分别测试、解释了Na3La9B8O27:Ln^3+和Na3La9B8O27:Tb^3激发光谱和发射光谱.比较了不同方法制备的荧光体的发光效率,并对产生的差异进行分析和讨论,助熔剂法得到的荧光体发光效率最高.

关 键 词:Na3La9B8O27:Ln^3+(Ln=Eu或Tb)  高温固相合成  溶胶-凝胶法  助熔剂

Preparation and Photoluminescent Properties of Phosphors Na_3La_9B_8O_(27):Ln~(3+)(Ln=Eu or Tb)
ZHANG Lu-ning,LI Zhi-hua.Preparation and Photoluminescent Properties of Phosphors Na_3La_9B_8O_(27):Ln~(3+)(Ln=Eu or Tb)[J].Journal of East China Jiaotong University,2008,25(4):80-84.
Authors:ZHANG Lu-ning  LI Zhi-hua
Institution:ZHANG Lu-ning,LI Zhi-hua(Department of Chemistry , Material Science,Sh,ong Normal University,Jinan 250014,China)
Abstract:Na3La9B8O27:Ln3+(Ln=Eu or Tb)phosphors have been prepared by solid state reaction,sol-gel process technique and fluxes technique,respectively.The optimal initial ratios have been determined in the solid state reaction process.The excitation and emission spectra of Na3La9B8O27:Eu3+ and Na3La9B8O27:Tb3+ are measured and explained.The different photoluminescent efficiency of the various prepared phosphors is studied and discussed.The phosphors fabricated by fluxes technique have the most luminescent efficiency...
Keywords:Na3La9B8O27
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