Characteristics on NOx adsorption and intermediates of LNT catalyst

Several NOx reduction technologies under development in recent years have now been commercialized, including selective catalytic reduction (SCR) with NH₃ or hydrocarbons, and Lean NOx Trap. The aim of the present study is to investigate characteristics on NOx adsorption according to the oxygen concentration, de-NOx performance according to lean/rich injection cycle and toxic intermediates at LNT downstram for lean-burn gasoline engine. Under oxygen of 6%, NOx storage capacity was the highest, showed the highest NOx conversion of 98%. The reason for this phenomena is because the excited oxygen atoms at high oxygen concentration increased oxidizing power of NO. Under low temperature of 205°C, LNT catalyst showed the least NOx conversion of 14% because its activity became lower, while the generation rate of toxic HNCO was highest as CO which is generated during the rich condition, reacts with NOx stored on Ba site.