Effect of pH on mechanical,physical and tribological properties of electroless Ni-P-Al2O3 composite deposits for marine applications

Successful co-deposition of fine particulate matter within an Electroless Nickel-Phosphorous (ENi-P) matrix is dependent on various factors like bath composition, particle compatibility with metallic matrix, bath reactivity (pH), particle size and their distribution. ENi-P deposits incorporating Al₂O₃/Alumina in a disperse phase have varied effects on properties and attributes like surface roughness (Ra), microhardness, wear resistance, corrosion resistance and surface morphology of the deposits obtained. This paper experimentally investigates the effect of alumina (1.55 g/L) on Ra, microhardness, surface morphology, deposition rate, wettability, wear resistance and corrosion resistance of ENi-P-Al₂O₃ composite deposits on mild steel substrates at bath pH 5, 7 and 9. Study reveals that optimum deposit parameters and deposition rates are achieved with bath pH. However, not much study has been undertaken concerning composite deposits obtained from higher bath pH or basic bath. This is attributable to the fact that at higher bath pH or alkaline baths, the bath gets unstable and eventually degrades or decomposes, thereby resulting in sub optimal or poor deposition. Hence, experimental investigations carried out by preparing suitable baths, operating under optimum conditions, and enabling successful composite deposition in acidic and alkaline baths have revealed that there is a significant improvement in the above mentioned properties of the as-deposited composite deposits, as the pH is increased from pH 5 to pH 9. This aspect can therefore be advantageously utilized for preparing various marine components like fasteners, nuts, bolts, washers, pipes, cables, components having relative motion etc.