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铜-氮化硅复合电沉积过程的交流阻抗测试分析
引用本文:杜克勤,邹恩义,王炜.铜-氮化硅复合电沉积过程的交流阻抗测试分析[J].大连铁道学院学报,1998(1).
作者姓名:杜克勤  邹恩义  王炜
作者单位:大连铁道学院应用化学系
摘    要:通过交流阻抗测试法研究了Cu-Si3N4复合电沉积过程Si3N4微粒对阴极电化学行为的影响,结果表明:Si3N4粒子在电极表面存在吸附,阴极极化增加,吸附增强;吸附粒子阻碍金属离子阴极放电沉积。

关 键 词:交流阻抗  复合电沉积  吸附

Electrochemical Impedance Spectroscopy Study of Si 3N 4 Particle Occlusion during Copper Electrodeposition
Du Keqin,Zhou Enyi,Wang Wei.Electrochemical Impedance Spectroscopy Study of Si 3N 4 Particle Occlusion during Copper Electrodeposition[J].Journal of Dalian Railway Institute,1998(1).
Authors:Du Keqin  Zhou Enyi  Wang Wei
Institution:Dept. of Applied Chemistry
Abstract:Analyses the effect of Si 3N 4 particles on the mechanism of copper Si 3N 4 coelectrodeposition during electrochemical impedance spectroscopy experiments.The main conclusinos are: (1) the particles adsorp at cathod surface and a rise in cathodic polarization enhances the adsorption effect;(2) the particle adsorption at electrode surface impedes the meta lion reduction,enhances the cathodic polarization.
Keywords:electrochemical impedance spectroscopy  co-electrodeposition  adsorption  
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