Evolving mechanism of eutectic carbide in as-cast AISI M2 high-speed steel at elevated temperature |
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Authors: | Bin Zhou Yu Shen Jun Chen Zhen-shan Cui |
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Institution: | (1) Jiangsu Key Laboratory of Advanced Metallic Materials, Southeast University, Nanjing, 211189, China |
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Abstract: | The evolution in type, size and shape of carbides in as-cast American Iron and Steel Institute (AISI) M2 high-speed steel
before and after annealing were investigated. The micromechanism which was responsible for those changes was also analyzed
and discussed. At the initial stage of reheating, metastable M2C-type carbide decomposed continuously. M6C-type carbide nucleated at the interface of M2C/γ firstly and grow from surface to center. Then MC-type carbide nucleated at both surface of M6C/M6C and inner of M6C. With the increasing decomposition of the metastable M2C-type carbide, the rod-shaped construction of eutectic carbide began necking, fracturing and spheroidizing gradually. Held
enough time or reheated at higher temperature, particle-shaped product aggregated and grew up apparently, while secondary
carbide precipitated in cell and grew up less significantly than the former. Based on the above microstructural observation,
the thermodynamic mechanism for decomposition of M2C carbide, for spheroidization of products, and for the growth of particles were analyzed. The rate equations of carbides
evolution were derived, too. It shows that the evolving rate is controlled by diffusion coefficients of alloy atoms, morphology
of eutectic carbides and heating temperature. |
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