负载型金属氧化物催化剂分解臭氧性能研究

制备了以活性炭和5A分子筛为载体的催化剂,考察了活性组分、相对湿度、活性组分含量以及空速等因素对其催化分解臭氧性能的影响,分析了臭氧在催化剂表面上的吸附和分解机理,得出以活性炭为载体的催化剂Mn-Ag-O/C具有良好的催化分解性能和较强的耐湿性能。     

Pt-Pd/Al2O3催化剂对甲烷的催化燃烧性能研究

采用浸渍法制备了Pt-Pd/Al2O3催化剂,以甲烷为实验气体,详细考察了空速、温度、甲烷浓度等反应条件对该催化剂活性的影响.实验结果表明,对于低浓度的甲烷,催化剂在350 ℃时活性达到75.3%,完全转化温度T99为400 ℃;温度、空速、甲烷浓度均对催化剂的活性产生影响,温度越高、空速越低、甲烷浓度越高,催化剂活性越好;在低浓度甲烷条件下,原料气中的氧气浓度对催化剂的活性影响较小;在20%O2/N2气氛中活化催化剂,其活性高于在纯N2气氛中活化的催化剂.     

Cr助剂对甲醇水蒸气重整制氢铜系催化剂性能影响的研究

通过正交试验初步确定催化剂的制备工艺,结合单因素实验对催化剂的组成进行了深入考察。在H2O/CH3OH摩尔比为1.3、液空速为1.5 h-1、反应温度为220℃和250℃的条件下,考察了铬助剂对催化剂性能的影响。结果表明,Cu/Cr质量比为1∶1时催化效果最佳,出口气体中CO的含量降低了50%,甲醇的转化率提高了20%。     

脱除甲醇、二甲醚的贵金属催化剂的研究

以氯铂酸或氯化钯为前躯体,γ-Al2O3为载体,采用过量浸渍法制备以钯或铂为前躯体的贵金属催化剂。采用固定床反应器,以二甲醚、甲醇等为入口气体,考察了反应温度、空速以及入口气体浓度等因素对催化剂性能的影响。实验结果表明:甲醇在185℃、二甲醚在195℃即达到起活温度,甲醇入口含量达到5000×10^-6,二甲醚入口含量达到7000×10^-6时,空速90000h^-1时,催化剂仍然有较高的转化率。     

常温(低温)CO氧化反应纳米金催化剂的研究

纳米金催化剂对CO低温氧化具有很高的催化活性,而且抗水性、稳定性都优于其他催化剂,具有广阔的应用前景。但在实验研究中发现,金催化剂的活性随制备方法、预处理条件、载体、金颗粒大小等的不同会出现较大差异。造成这种差异的原因,从根本上说是由于人们对这种新型催化剂的活性位数目、性质还不能实现有效控制。本文在简要回顾多种因素影响金催化剂活性的实验事实的基础上,综述了对活性本质的最新研究成果,以期为高活性、高稳定性的金催化剂的制备提供理论参考。     

Pt/SDB疏水催化剂的制备及其用于水相消氢

将疏水催化剂应用于水相消氢可以提高电解水制氧装置的氧气纯度.本文以聚苯乙烯 - 二乙烯基苯(SDB)树脂为载体制备了高度分散的Pt/SDB疏水催化剂,并将其应用于水相消氢实验中.结果表明,6%的Pt/SDB催化剂消氢活性最高.在H2/O2空速(GHSV)10 000 h-1,水流量30 L/h,温度60 ℃时,氢气消除率达到了80%.采用X射线衍射、X射线光电子能谱、扫描电子显微镜、热重分析仪对制备的催化剂进行了表征.分析发现,制备的催化剂具有良好的疏水性,Pt已被还原为0价态并以高度分散态存在,平均粒径小于5 nm.     

阳极氧化法制备消氢催化剂金属载体及其性能研究

用阳极氧化法制备消氢催化剂金属载体,以磷酸为电解液考察了温度、氧化时间、氧化电压、电流最大密度以及水封处理对氧化膜表面的影响,用SEM表征方法对多孔氧化铝膜进行了表征.结果表明,氧化膜厚度达13.4 μm.孔径达100 nm.将Pt-Pd负载在自制的载体上制成消氢催化剂,该催化剂可在常温、氢气浓度1.1%～1.3%、空...     

臭氧对船舶废气中氮氧化物的氧化试验研究

用管式反应器试验研究了反应温度、[O3]/[NO]对臭氧氧化NO的影响.结果表明,O3/N2/O2体系在常温、200℃、275℃下均不发生反应,N2不能被O3氧化;在O3/NO/N2/O2体系中,NO主要氧化为NO2,只有1～6(10-6)其他氮氧化物生成.如N2O and N2O3.当[O3]/[NI]=1、反应温度分别为常温和200℃时,NO氧化率都达到100%,而在275℃时,NO氧化率只有72%.表明反应温度影响显著,其原因主要与较高温度下O3分解加快有关.O3在不同温度下的分解试验发现,O3在常温下分解很慢;200℃时分解加快,在反应器中停留9 S时,O3的分解率为59%,而275℃时分解更快,在反应器中停留9 s时,O3的分解率为80%.试验结果还表明,NO氧化率与[O3]/[NO]成线性关系.     

低温催化燃烧VOCs铜锰混合型催化剂的研究

考察了2种铜锰混合型催化剂低温催化燃烧各种VOCs的反应活性,以及这2种催化剂的抗湿性能和受空速的影响.结果表明,2种催化剂都能在低于260℃完全催化燃烧VOCs;1号催化剂的催化活性和抗湿性能更优.通过BET,XRD.XPS,SEM等表征发现,2种催化剂呈现无定形状态,表面孔分布特别丰富,2种催化剂都有大的比表面积,这些因素就促使2种催化剂对VOCs有高的低温活性.通过XPS分析,Cu2p3/2显示Cu元素主要是 2价,Mn2p3/2显示Mn元素主要是 4价.     

络合沉淀法制备纳米Co3O4的工艺研究

以Co(NO3)2·6H2O等钴盐,NH3·H2O,H2O2和NaOH为原料,采用络合沉淀法在水溶液中直接制备出了纳米Co3O4,通过X射线衍射仪(XRD)和扫描电镜(SEM)等观测,讨论了不同反应物、反应物之间的摩尔比和反应温度等制备条件对反应产物组成和结构的影响.研究结果表明本制备工艺能够制得纯度高,分散性能好,颗粒分布均匀,结晶度较高的球形纳米Co3O4.纳米Co3O4的最佳制备工艺条件[Co(NH3)6](NO3)3与Co(NO3)2 的摩尔比为2.5～31,NaOH 与Co(NO3) 2的摩尔比为0.9～1.21,反应温度为80℃.     

33rd International Conference on Ocean,Offshore and Arctic Engineering （OMAE2014）

正San Francisco,California,June 8-13,2014.OMAE 2014 is the ideal forum for researchers,engineers,managers,technicians and students from the scientific and industrial communities from around the world to:·meet and present advances in technology and its scientific support;·to exchange ideas and experiences whilst promoting technological progress and its application in industry·to promote international cooperation in ocean,offshore and arctic engineering.In line with the tradition of excellence of previous OMAE conferences,more than 900 technical papers are planned for presentation.Outreach for Engineers Specialty Forum This Specialty Forum is designed for students and professionals who may not be familiar with the Ocean and Offshore industry,as well as those who have just recently specialized in this field.     

Errata

正In the paper"Influence of Fouling Assemblage on the Corrosion Behaviour of Mild Steel in the Coastal Waters of The Gulf of Mannar,India"in Vol.12,No.4,Page:509,References were lost,and the two authors’biographies were identical.The correct text is shown below.We apologize to the authors and our readers for any inconvenience caused by the errors.     

Journal of Marine Science and Application 2014 Sum. Contents

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联合作战计划和执行系统

全球指挥控制系统(GCCS)实施当前美国海军网络中心战信息基础设施的联合计划网络。联合作战计划和执行系统(JOPES)支持GCCS实现联合计划。JOPES有两类计划：时间不限的精密预案计划生成作战计划、方案计划或职能计划；时间敏感的危机行动计划生成作战命令或战役方案。前者在和平时期创建的作战计划是后者的计划基础，加速应付危机的能力。     

Recent progress on wave induced loading measurements in warships

Recent measurements of wave induced hull strain and flexure in RN warships are presented together with the derivation of the current design criteria for extreme hull girder bending loads. The history of the development of the shipboard instrumentation used is given and recent developments to improve the quality and ease of analysis of the data are described. An unexpectedly high transverse asymmetry in the longitudinal strains measured in destroyers is shown to be the result of a combination of vertical and lateral bending in oblique seas. Finally recent theoretical comparisons between the loading of Deep-Vee hulls and conventional UK rounded bilge hulls are presented which demonstrate the higher loading experienced by this type of hull form.     

The 11th International Conference on Hydrodynamics (ICHD 2014)

正19–24 October 2014 SingaporeCONFERENCE THEMES The overall aim of the ICHD Conference is to provide a forum for participants from around the world to review,discuss and present the latest developments in the broad discipline of hydrodynamics and fluid mechanics.The first International Conference on Hydrodynamics(ICHD)was initiated in 1994 in Wuxi,China.Since then,9 more ICHD conferences were held subsequently in Hong Kong,Seoul,Yokohama,Tainan,Perth,Ischia,Nantes,Shanghai and St Petersburg.Evidently the ICHD conference has become an important event among academics,researchers,engineers and operators,working in the fields closely related to the science and technology of hydrodynamics.The 11th ICHD will be held in Singapore in 2014.     

第十二届深水操作会议和展览会(英文)

正November 4-6,2014Moody Gardens HotelConvention Center/Galveston,TX The Deepwater Operations Conference and Exhibition is celebrating its 12th anniversary this year.This growing event will continue the tradition of excellence in addressing operational challenges involved in developing deepwater resources.We will return to the Moody Gardens Hotel and Convention Center on November 5-7,2014 in Galveston,Texas.     

Eastbound or westbound ?

In terms of equal sailing distances, where is the inflexion when ships depart from ports in the Asian Continent to New York via Suez and/or Panama？
The answer is China South Port Group （Hong Kong, Shenzhen and Guangzhou）.     

Impact of regulation on the performances of long-distance transport services: A comparison of the different approaches in Sweden and Norway

Despite the many socio-economic similarities between Sweden and Norway, differences in jurisdiction, organisation, cooperation, and financing of long-distance passenger train and coach services have led to the development of four distinctively different ways of serving the markets. This paper describes how the train and coach markets have developed in the two countries, with emphasis on regulatory and industrial structure and a couple of performance variables.Looking at passenger rail, both countries separated infrastructure from operation over a decade ago. However, while Norwegian rail is characterised by an almost monopoly supplier, rail services in Sweden are partly decentralised to the responsibility of county authorities and are widely subjected to competitive tendering. The rest of the network is about to be opened up for on-the-track competition. Swedish Rail (SJ) has spent the last decades consolidating its core business (passenger rail) and sold out its other businesses. In contrast, the Norwegian state rail (NSB) has expanded its business to become a major bus operator and property owner, with extensions also into the Swedish market.The coach industry was more recently deregulated in both countries. The Swedish coach market is dominated by privately owned companies operating services to and from Stockholm. In Norway, state-owned NSB is a major coach operator on medium distance routes, and is also the largest partner of Nor-Way Bussekspress which totally dominates long-distance coach services. Further, the Norwegian coach market is characterised by cross-ownership and cooperation which has enabled an extensive route network which covers most of Norway.We find distinct differences in achievements in the two modes and in the two countries. Swedish rail services have succeeded in winning market shares and in renewing and developing both infrastructure and service levels to a greater extent than the Norwegian model. On the other hand, the Norwegian coach market seems to be more developed and efficient compared to its Swedish counterpart.The paper concludes with a discussion on the possible links between the different approaches and the performance observed, with the aim to stimulate further and more detailed research on some important issues.     

某海港码头的撞损修复

依据码头撞击受损区域调查检测结果,对受损构件提出合理的修复方案,为码头的安全运行提供保障。