镍-钼-磷/聚四氟乙烯复合电沉积工艺研究

在镍-钼-磷(Ni-Mo-P)合金电镀液中加入聚四氟乙烯(PTFE)制得了镍-钼-磷/聚四氟乙烯(Ni-Mo-P/PTFE)复合镀层.研究了镀液主要成份及工艺条件对复合镀层的影响,优选出一种较佳的工艺条件及复合镀液配方.由复合镀层性能测试结果发现,与Ni-Mo-P合金相比,由于PTFE的加入,提高了复合镀层的减摩性,但结合力与硬度略有下降.     

镍—聚四乙烯复合电沉积机理的研究

利用电化学测试方法研究了镍－聚四乙烯复合电沉积的过程,依据测试分析,提出了相关的物理模型和数学模型,并建立了PTFE粒子在镀层的覆盖度与电极过电位、微粒在镀液中悬浮量和拌搅拌强度等因素之间的关系式,揭示了PTFE与镍共沉积时电极过程的作用机理。     

镍钨(D)合金刷镀工艺的优化

对镍钨（D）合金刚镀中电极运动速度，施镀电压两个参数对结合力及硬度的影响进行试验．从而得到镍钨(D)合金镀液的优化工艺参数，通过优化试验，提出了获得最高硬度及最佳结合力镀层的施镀工艺。     

镍-聚四乙烯复合电沉积机理的研究

利用电化学测试方法研究了镍-聚四乙烯复合电沉积的过程.依据测试分析,提出了相关的物理模型和数学模型.并建立了PTFE粒子在镀层的覆盖度与电极过电位.微粒在镀液中悬浮量和拌搅拌强度等因素之间的关系式.揭示了PTFE与镍共沉积时电极过程的作用机理.     

n-SiC/Ni复合电刷镀层制备及性能试验研究

首先制备镀镍层,并通过表面粗糙度和硬度的对比,选出一组电压、镀液温度和镀笔移动速度参数作为复合镀的基础。将不同浓度的n-SiC加入镀液中制备复合镀层,从表面粗糙度、硬度、耐蚀性和结合强度等方面,得出最佳纳米颗粒浓度数值。     

稀土元素在铬酸镀铬中的作用与研究概况

在铬酸镀液中加入稀土添加剂能降低镀液的铬酸浓度，改善镀液性能，提高镀层质量，达到节约原材料，降低能耗，减少污染的目的，因而具有较好的应用前景。     

电刷镀技术的研究进展

本文综述了近年来电刷镀技术在剧镀液、刷镇工艺、镀层强化机理、实际应用等方面的研究进展，并指了出该项技术的发展趋势。     

镍／聚四氟乙烯复合电镀新工艺的研究

利用电沉积方法制取了镍/聚四氟乙烯复合膜，研究了电流密度、温度、表面活性剂、预镀等因素对复合镀膜的影响，从而得取了最佳工艺条件，结果表明镀膜质量良好，耐磨性大大提高。     

电刷镀Ni—Fe—W合金的工艺研究

进行了电刷镀技术在紫铜基体上刷镀Ni-Fe-W合金的工艺研究。结果表明,所用的合金镀液有较好的刷镀性能,镀层在回火时有明显的二次硬化现象,在400℃回火时最高硬度可达935H_、     

聚氨酯泡沫表面电沉积镍工艺研究

采用化学镀镍、电沉积镍工艺在聚氨酯泡沫表面电沉积镍,研究了pH、电流密度、温度和沉积时间对镀层厚度和质量的影响.利用金相显微镜,扫描电子显微镜( SEM)和能量散射分光仪(EDS)对镀层横截面、表面形貌和成分进行了观察与检测.研究结果表明:镀液pH为4.2时镀层厚度最大为76 μm;镀层厚度随着电流密度的升高而增大,镀...     

镍/聚四氟乙烯复合电镀新工艺的研究

利用电沉积方法制取了镍/聚四氟乙烯复合膜.研究了电流密度、温度、表面活性剂、预镀等因素对复合镀膜的影响,从而得取了最佳工艺条件,结果表明镀膜质量良好,耐磨性大大提高.     

Investigation on mechanism of the improvement in tribological properties of carbon fiber reinforced polytetrafluoroethylene composites by surface treatment

Tribological properties of polytetrafluoroethylene (PTFE) composites filled with differently surface treated carbon fibers (CF), sliding against GCr15 steel under dry sliding conditions, were investigated on a block-on-ring M-2000 tribometer. Experimental results reveal that rare earths (RE) surface treatment reduces the friction and wear of CF-reinforced PTFE (CF/PTFE) composites. Scanning electron microscopy (SEM) investigation of worn surfaces of CF/PTFE composites shows that cracks or pores are visible on the worn surfaces of untreated and air-oxidated composite, while no crack and very few pores present on the worn surface of REtreated composite. The fiber-friction-angling effect makes carbon fibers angled and oriented along the frictional shearing force, and finally parallel to the friction surface, which makes interfacial adhesion become a key factor to tribological properties of CF/PTFE composite. With strong interfacial adhesion between carbon fiber and PTFE after RE surface treatment, carbon fibers are not easily detachable from the PTFE matrix in the process of fiber-friction-angling, which prevents the rubbing-off of PTFE, and accordingly improves the friction and wear properties of the composite.     

高频脉冲电镀镍钴合金的内应力

研究了脉冲频率、硫酸钴浓度对高频脉冲电镀Ni—Co复合镀层微观形貌与内应力的影响．高频脉冲电镀获得的沉积层表面比直流电镀致密、均匀、孔隙率低、内应力低．随脉冲频率的升高,Ni—Co镀层的内应力先减小后增加,并在80kHz取得最小值．随硫酸钴浓度的增加,镀层的内应力先增大后减小,在30g/L取得最大值．     

Microstructure and Contact Fatigue Behavior of Nano—SiO2／Ni Coating Prepared by Electro—Brush plating

Introduction　　Ingeneral,compositecoatingispreparedbyco depositingfineparticlesofmetallicornon metalliccompoundswiththemetalionsinordertoimprovematerialpropertiessuchaswearresistanceandlubrication[1,2 ] .Nickel,copper,cobalt ,silver ,nickel phosphorous ,…     

Experimental study on frictional and sealing performances of packing rings in an oil-free gas compressor

To enhance the reliability and to extend service life of packing rings, tribological and sealing performances are investigated based on the experimental results. Friction force, leakage rate and power consumption of three materials of pressure packing seals are measured in a refitted vertical gas compressor. The rings are made of common filled polytetrafluroethylene (Filled PTFE), PTFE reinforced with 30% mass fraction carbon fiber (30%CF+PTFE), and carbon-carbon composites infiltrated with PTFE (C/C+PTFE), respectively. It is found that packing rings will periodically vibrate with the periodic vibration of pressure packing after the travel direction of motion abruptly turns to the reverse direction. Furthermore, the amplitude of vibration slows down with the increasing crank angle. Approximate value of friction force is available by multiple-point fast Fourier transformation (FFT) employed to process the experimental results by reducing the impact of vibration to a great extent. Of three materials of rings employed in experiments, Filled PTFE presents minimal leakage rate accompanied with maximum power consumption. And 30%CF+PTFE exhibits minimum friction power and moderate leakage rate. As for C/C+PTFE, its high mechanical and thermal properties are favorable factors to enhance the ability of operating under high pressure and velocity and to improve the wear resistance. Unfortunately, this also leads to a large leakage rate. Comprehensive consideration should be taken into to evaluate the availability, reliability and service life for a type of packing ring under dry running conditions.     

d区主要元素合金电镀的理论分析与实践

本文简述了d区主要元素合金电镀的意义;从电化学、络合物和原子结构、晶体结构等基本理论出发,以合金电镀实践为依据,对d区主要元素的合金电镀的可能性在理论上进行了较详细的分析与阐述,对铁族元素的过电位与d区主要元素共沉积的关系以及工艺参数对合金共沉积的影响也作了简要分析。本文还对d区主要元素的合金电镀实践提供了有力的例证。事实表明,对d区主要元素进行合金电镀在理论上和实践上都是可行的。     

复合反渗透膜对模拟放射性核素的截留性能研究

配制了模拟放射性废水,在＂预处理→反渗透＂系统上将废水含盐量、pH、操作压力和回收率对复合反渗透膜对模拟放射性核素的截留率的影响进行了研究.结果显示：（1）Ni,Mn,Co的截留率随废水水质和操作条件的不同而变化,变化范围分别约为81.8%～98.7%,81.3%～100%,75.9%～98.8%.（2）反渗透是处理含有Ni,Mn,Co废水的有效方法,其中对锰的截留效果优于镍和钴,锰的截留率最高几乎达到100%.     

纯铜表面镍硼合金涂层的制备

用化学沉积技术制备了Ni-B表面强化铜基材料，研究了表面涂层的显微组织、涂液的成分对镍硼沉积速率的影响及有关性能．结果表明，用化学沉积技术能在纯铜表面形成一层均匀、连续的镍硼硬化层，镍硼涂层的沉积速率由涂液中的NiCl2，KBH4，NaOH，稳定剂和H2NCH2CH2NH2的浓度控制，涂层是非晶态组织和少量过饱和镍固溶体的混合物，热处理后在涂层中析出Ni2B和Ni3B化合物，改善了铜的表面硬度和耐磨损性能，对铜的电阻率影响不大．