稀燃条件下甲醇汽油混合燃料颗粒物排放特性

在1台GDI增压汽油机上,进行了稀燃发动机燃用M0,M10和M20(其中M0为汽油,M10为甲醇体积分数10%、汽油体积分数90%的混合燃料,以此类推)甲醇汽油混合燃料的试验,研究了在稀燃条件下甲醇汽油混合燃料对GDI发动机颗粒粒径分布特性、数量浓度特性和质量浓度特性的影响。试验结果表明:在稀燃条件下,随着甲醇比例的增加颗粒数量浓度峰值逐渐增大,颗粒数量浓度随粒径分布呈现出双峰分布;颗粒中的核态颗粒和积聚态颗粒的总数量都随甲醇比例的增加而增加,其中M20的积聚态和核态颗粒数量浓度最大;颗粒粒径峰值都随着甲醇比例的增加逐渐增大,并且核态颗粒粒径峰值主要集中在20.54~31.62nm,积聚态颗粒粒径峰值主要集中在56.23~100nm;颗粒质量浓度随甲醇比例的增加而增大,粒径分布在316~700nm的积聚态颗粒明显增多,积聚态颗粒质量浓度随粒径分布的范围明显增加,质量浓度也相应增加,而粒径分布在56.23~316nm范围内的颗粒质量浓度却在降低。     

EGR对轻型柴油机超细颗粒排放的影响

基于1台匹配废气再循环(EGR)系统的轻型柴油机,在中低负荷下研究了EGR对发动机超细颗粒排放的影响.研究发现:各工况下,随EGR率的增大,颗粒排放中核模态颗粒数量浓度在各粒径下有所减少,核模态颗粒排放数量速率和质量速率有减少趋势,且在最大扭矩转速的低负荷工况更加明显;积聚态颗粒数量浓度在各粒径下都增加,积聚态颗粒排放数量和质量速率也都增加,且中负荷时更加明显,而积聚态颗粒数量浓度峰值粒径基本没有改变.随EGR率的增大,总的超细颗粒排放数量速率在最大扭矩转速的低负荷工况减小,而其他工况都明显增加.由于积聚态颗粒总质量浓度占超细颗粒总质量浓度比例达99%,所以超细颗粒排放质量速率也都增加,几何平均粒径也都明显增大.在低负荷较低EGR率和中负荷较大EGR率时,过高的喷油压力都将使超细颗粒排放数量速率增加.     

测量条件对柴油机排放PM尺寸分布的影响

研究了不同测量条件对柴油机PM尺寸与浓度分布测量的影响,在一台单缸柴油机上用SMPS测量装置测量了不同运转条件下柴油机PM排放,试验中采用不同的稀释比、稀释空气温度、取样点位置等,在大量的试验研究基础上,分析了柴油机PM排放的特征和主要影响因素。结果表明,随稀释比增加,PM尺寸趋向于累积模式分布或粗粒子模式分布,其浓度趋于降低;随着稀释空气温度的升高,PM质量和数量也相应降低,低负荷时PM峰值浓度移向细小颗粒的碳核模式区域;取样点位置远离排气出口,PM浓度逐渐减小,累积模式尺寸的PM数增多。     

铁基燃油添加剂对柴油机颗粒排放影响的试验研究

基于发动机试验台架,对柴油中添加微量的铁基燃油添加剂进行了试验,从颗粒物数量浓度和粒径的分布特性、排气烟度、颗粒物的氧化特性等方面研究了燃油添加剂对柴油机颗粒物排放的影响。研究结果表明：燃油添加剂能降低柴油机排气温度和排气烟度。加入添加剂后,核模态颗粒数量浓度增加,峰值粒径也增加;积聚态颗粒数量浓度无明显变化;颗粒物总数量浓度增加,但添加剂浓度对颗粒数量浓度影响较小。添加剂使颗粒物中SOF含量增加,同时也使得微粒的氧化表观活化能和起燃温度都降低。     

EGR废气组分和温度对柴油机颗粒力学特征的影响

围绕柴油机颗粒的微观力学性能,针对不同EGR废气组分和温度条件下产生的颗粒,采用颗粒粒径分析仪和原子力显微镜等分析手段,研究了颗粒粒径、数量和质量浓度的变化规律,探讨了EGR废气组分和温度对颗粒弹性模量、团聚力大小和主要作用形式等微观力学性能的影响。研究结果表明,随着EGR废气温度升高,核模态颗粒总数量浓度变化不大,积聚态颗粒总数量浓度有较大幅度增加,颗粒的弹性模量逐渐增大,结构刚性逐渐增强,颗粒间的团聚力逐渐增加,团聚力作用的主要形式由液桥力逐渐向范德华引力转变;与引入废气时相比,分别引入N_2和CO_2时,颗粒间的团聚力分别主要以范德华力和液桥力形式存在;废气中的N_2是导致采用EGR后积聚态颗粒粒径增加、数量和质量浓度升高、结构刚性和团聚力增强的主要气体成分,废气中的CO_2可以显著降低积聚态颗粒排放数量和质量浓度、降低颗粒的结构刚性和团聚力。     

环境温度对缸内直喷汽油车颗粒物排放特性的影响

利用电子低压冲击仪(ELPI)对一台满足国Ⅴ排放标准的缸内直喷汽油车进行了颗粒物排放特性研究。试验按照NEDC测试循环在转鼓试验台上进行,分别测量车辆在-15℃,-7℃和25℃下的颗粒物排放。通过对试验结果的研究表明:3个温度下,颗粒物的数量浓度随温度的下降大幅上升,粒径分布范围逐渐变大,均在相同粒径下出现峰值;颗粒物体积浓度随粒径的增大而增大;数量浓度对表面积浓度的影响大于体积浓度,尤其在-15℃下,这种影响更加显著。通过对颗粒物的瞬态排放结果的分析发现:3个温度下,颗粒物的排放主要集中在NEDC循环前200s,数量浓度随车辆的加速而上升,随减速而下降;在-15℃下,在整个NEDC循环的加速工况均出现表面积浓度的排放峰值,且峰值之间较为接近。     

颗粒计数器一级稀释比对颗粒数浓度测量结果一致性影响的研究

文章以某重型柴油发动机为研究对象,探究了颗粒计数器不同一级比对颗粒数浓度测量结果一致性的影响。研究表明:颗粒计数器不同稀释比对原排PN测量影响较小,稳态工况点的最大偏差为6.8%,热态WHTC循环的最大偏差为3.7%,在设备测量精度(±10%)范围内,测量结果的一致性较好;颗粒计数器不同稀释比对加装DPF后的PN测量结果影响较大,稳态工况点的最大偏差为120%,热态WHTC试验的PN循环比排放量最大偏差为230%。     

车用高压共轨柴油机瞬态工况微粒排放粒度分布的分析

对高压共轨柴油机稳态与瞬态工况下的微粒排放粒度分布进行了实验研究。结果表明,高压共轨柴油机排气微粒粒径大部分处于250nm以内,超细微粒占绝大多数。稳态工况下,随负荷增加微粒数量浓度分布曲线峰值逐渐向大粒径方向移动,大负荷工况下峰值开始进入积聚态区域。在瞬态工况下,微粒粒度分布曲线呈单峰形态,平均数量浓度分布峰值位于核态区域,峰值区间为15~25nm。在同一负荷(当量比0.5)下,稳态工况的核态微粒的数量、表面积和体积浓度均较稳态工况大幅度上升;随着瞬变率的增大,核态微粒数量浓度增加而积聚态微粒数量浓度下降。     

燃料特性对柴油机排放微粒粒度分布的影响

利用微粒粒径分析仪进行测试,以研究不同理化特性的燃料对直喷式柴油机微粒排放粒度分布的影响规律,分析了柴油机微粒排放粒度分布特征。结果表明,柴油机的微粒排放大部分在1μm以下,以粒径50nm为分界,基本可以分为核态和积聚态两种。测试中微粒粒数浓度随着稀释比的增加而加大,同时微粒分布趋向核态。与转速相比,负荷变化对微粒粒度分布的影响较大,随着负荷的增大,核态PM所占比例减小。与欧Ⅲ柴油相比,生物柴油燃料核态微粒较多,积聚态微粒较少。天然气合成柴油燃料的核态和积聚态微粒浓度均低于欧Ⅲ柴油燃料,但其积聚态微粒浓度高于生物柴油燃料。     

粒状土与结构接触面强度特性粒径效应影响研究

为研究颗粒粒径对典型粒状土与结构接触面剪切特性的影响,开展了不同粒径范围粗粒土与混凝土接触面大型直剪试验,分析颗粒粒径对接触面剪切强度及接触面强度参数的影响规律,探讨了接触面剪切强度的粒径效应影响机理。结果表明：接触面剪切强度随土体颗粒粒径的增大而明显增大,且当颗粒粒径与结构表面粗糙形貌比值接近1时,其继续增大对接触面剪切强度影响不再明显;不同剪切位移处接触面剪切应力与法向应力均能较好地满足摩尔库伦破坏准则,剪切过程中接触面内摩擦角随剪切位移的增大而增大并逐渐趋于稳定;而不同粒径条件下接触面表观黏聚力随剪切位移的变化规律有着明显的差异;颗粒粒径的增大能显著提高接触面表观黏聚力,对接触面最大内摩擦角无明显影响。     

柴油机DOC+CDPF系统的过滤和再生性能试验研究

基于氧化催化转化器(DOC)+催化型颗粒捕集器(CDPF)系统开展了发动机台架试验,对比系统前后的颗粒物粒径分布,获得了系统的过滤效率,同时也测量了该系统在各稳态工况下的再生效率.研究结果表明:该系统对颗粒物的过滤效率在发动机的各个工况均能达到95%以上;系统前的颗粒物数量浓度呈单峰分布,主要为核模态;系统后颗粒物数量浓度呈双峰分布,峰值分别在10 nm和150 nm左右,且10 nm左右波峰峰值最大;再生效率随着再生温度的升高呈上升趋势,测试系统的起燃温度在250℃以下;再生效率均随着再生时间的增加而增加,但在再生后期明显变缓;在较高的再生温度时,颗粒担载量增大将有利于提高再生速率.     

二次喷射时刻对 GDI 汽油机颗粒物排放的影响

研究了缸内直喷汽油机在不同二次喷射时刻条件下的颗粒物粒径分布特性。试验工况为最大扭矩转速2000 r／min工况,负荷率分别为10％,30％,60％。试验结果表明：不同二次喷射时刻下,缸内直喷汽油机颗粒物粒径呈单峰分布,低负荷数量峰值在对应的积聚模态70 nm附近。低负荷下,合理优化二次喷油时刻可以降低颗粒物排放;中等负荷时,单次喷射的颗粒物排放远低于二次喷射。     

Reaction characteristics of the diesel oxidation catalyst of particulate matters from the diffusion flame of a oiler burner

The objective of this experimental study is to investigate the characteristics of the size distribution and the number concentration of PM (particulate matters) emitted from the diffusion flame of a boiler burner, which has the same type of combustion as a diesel engine. This study is performed to investigate the emission characteristics of nanoparticles generated from diffusion combustion in diesel fuel, and it considered fuel factors and the reaction characteristics of the nanoparticles on the DOC (Diesel oxidation catalyst). The factors examined in this experiment included the sulfur content in the fuel, the blend of the diesel fuel containing biodiesel and bio-ethanol, and the concentration of engine oil (0.1% and 1.0%) blended with diesel fuel. The particle size distribution of the nanoparticles exhausted from the boiler burner was measured by an SMPS (scanning mobility particle sizer). The number concentration of PM that were smaller than 70 nm in diameter greatly increased in the rear of the DOC when fuel containing 250 ppm of sulfur was used. The experiment also suggested that the particle number concentration in both the front and rear of the DOC was lower when ULSD (ultra low sulfur diesel) fuel blended with biodiesel and bio-ethanol, which are oxygenated fuels, was used than when only ULSD fuel was used. The higher the content of engine oil in the fuel, the higher the particle number concentration was in the front and rear of the catalyst. When the first dilution air temperature is increased from 30°C to 180°C, the nanoparticle number concentration dramatically dropped in the rear of the catalyst when fuel containing 250 ppm of sulfur was used, while the particle size distribution remained almost the same when the fuel with engine oil was used.     

Effect of Heavy-Duty Diesel Engine Operating Parameters on Particle Number and Size Distribution at Low Speed Condition

Experiments and simulations were used to investigate the effect of a range of engine operating parameters and fuel characteristics on the particle size and particle number (PN) concentration at low speed and idle speed condition. The occurrence, size, and concentration of particles were tested against a range of parameters including start of injection (SOI), common rail pressure, exhaust gas recirculation (EGR) ratio and load. The results showed that the homogeneity of the mixture had the greatest impact on particle size and number concentration. The performance of particle is different at different levels of load. The particle were of nucleation mode at idle condition, and the cold idle particles had a slightly larger diameter than those produced at hot idle. By using the diesel and under high load, at EGR ratios of less than 20 %, most particles were of nucleation mode. At EGR ratios exceeding 20 %, nucleation-mode particles were gradually replaced by accumulation-mode particles. At EGR ratios above 30 %, most particles were of the accumulation mode. Under the same load, gasoline compression ignition produced particles of smaller size and reduced particulate mass (PM). The use of gasoline extended ignition delay, as the high volatility and octane number of the fuel improved the homogeneity of the mixture. Finally, a linear relationship was found between PM and PN. The relative contribution of the different factors to the formation of nucleationor accumulation-mode particles was investigated.     

不同裂解条件对甲醇-柴油高温裂解产物的影响研究

采用石英管式流动反应器试验装置,配置不同体积掺混比(M0,M5,M10,M15)的甲醇-柴油混合燃料作为试验燃料,采集了混合燃料在不同裂解温度和甲醇掺混比下的裂解产物。应用气相色谱质谱联用仪GC-MS,对不同裂解条件下12种烃类产物的摩尔分数变化规律进行了研究;采用微克天平和扫描电镜SEM,对甲醇-柴油混合燃料裂解生成的炭烟产率及形貌特征的变化规律进行了研究。结果表明:裂解过程中,裂解温度高于973 K时,烷烃和芳香烃的摩尔分数变化率降低,芳香烃的摩尔分数增加,相比于923 K,裂解温度为973 K,1023 K和1073 K时,炭烟产率分别增加了1.7倍、5.1倍和11.6倍;甲醇掺混比增加,烃类物质摩尔分数和炭烟产率降低;裂解温度增加,炭烟的平均粒径降低,乙烷、丙烷、丁烷及丙烯、丁烯、丁二烯的浓度降低;甲醇掺混比增加,炭烟的平均粒径降低,乙烯的摩尔分数增加。     

Experimental investigation and comparison of nanoparticle emission characteristics in light-duty vehicles for two different fuels

In recent years, particle number emissions rather than particulate mass emissions in automotive engines have become the subject with controversial discussions. Recent results from studies of health effects imply that it is possible that particulate mass does not properly correlate with the variety of health effects attributed to engine exhaust. The concern is now focusing on nano-sized particles emitted from I. C. engines. In this study, particulate mass and particle number concentration emitted from light-duty vehicles were investigated for a better understanding of the characteristics of the engine PM from different types of fuels, such as gasoline and diesel fuel. Engine nano-particle mass and size distributions of four test vehicles were measured by a condensation particle counter system, which is recommended by the particle measurement program in Europe (PMP), at the end of a dilution tunnel along a NEDC test mode on a chassis dynamometer. We found that particle number concentrations of diesel passenger vehicles with DPF system are lower than gasoline passenger vehicles, but PM mass has some similar values. However, in diesel vehicles with DPF system, PM mass and particle number concentrations were greatly influenced by PM regeneration. Particle emissions in light-duty vehicles emitted about 90% at the ECE15 cycle in NEDC test mode, regardless of vehicle fuel type. Particle emissions at the early cold condition of engine were highly emitted in the test mode.