Predictive Model for Corrosion Rate of Oil Tubes in CO2／He S Coexistent Environment Part Ⅰ： Building of Model

Based on an analysis of the existing models of CO2 corrosion in literatures and the autoclave simulative experiments, a predictive model of corrosion rate (γcorr ) in CO2/H2S corrosion for oil tubes has been established, in which γcorr is expressed as a function of pH, temperature (T) , pressure of CO2 ( Pco2 ) and pressure of H2S (PH2S). The model has been verified by experimental data obtained on N80 steel. The improved features of the predictive model include the following aspects: ( 1 ) The influence of temperarare on the protectiveness of corrosion film is taken into consideration for establishment of predictive model of the γcorr in CO2/H2S corrosion. The Equations of scale temperature and scale factor are put forward, and they fit the experimental result very well. (2)The linear relationship still exists between In γcorr and In Pco2 in CO2/H2S corrosion ( as same as that in CO2 corrosion). Therefore,a correction factor as a function of PH2s has been introduced into the predictive model in CO2/H2 S corrosion. ( 3 ) The model is compatible with the main existing models.     

Predictive Model for Corrosion Rate of Oil Tubes in CO_2/H_2S Coexistent Environment Part Ⅰ: Building of Model

Introduction　　Sincethecorrosionofoiltubesinbrinesolutionscontainingcarbondioxide (CO2 )andhydrogensulfide(H2 S)gasesisasevereprobleminengineering ,itisveryurgenttobuildapredictivemodelofthecorrosionrate(rcorr)foroiltubesinCO2 /H2 Scoexistentenvironment …     

油井爆炸事故原因分析

对某油井爆炸事故进行了深入细致的调查研究,对爆炸的井口设备和井下管材残片逐一进行了分析检查。认为油井爆炸发生于油管内部,爆炸性质属于化学爆炸。爆炸原因是在油管里注入了H2O2,且关闭了所有与油管连通的阀门。H2O2在密闭的油管里分解出大量氧气和热量,并与油管内的油、气发生剧烈反应,最后发生了燃烧爆炸。对分析结论用油管实物进行了水压验证试验,对油井管化学爆炸和物理爆炸的特征用金相分析和断口微观分析方法进行了验证。