The role of nano additives for biodiesel and diesel blended transportation fuels

The energy crisis is due to two reasons, one is the rapid increase in worldwide population and the other is changing living style of human beings. The fossil fuel is also a major contributor to add the harmful pollutants into the atmosphere. Fuel modifications play a major role in increasing engine efficiency and reducing emissions. In the present investigation focused on fuel modifications in diesel engine. Initially the single cylinder diesel engine was operated with 20MEOM, 40MEOM, 60MEOM, 8MEOM and 100MEOM without additives with diesel at different loads at constant rated speed. From the experimental study proved that 20MEOM is the best fuel ratio compared to other blends. In second phase based upon first phase results the engine was operated 20MEOM blended fuel with adding 50 ppm copper oxide nano additives with diesel using solgel process. From the results, the brake thermal efficiency was 2.19% improved compared than 20MEOM blend without additive at full load condition. Emissions of HC, CO and smoke were considerably reduced. The present analysis reveals that the biofuel from mahua oil with nano additives is quite suitable as an alternate fuel for diesel engine.     

Performance and emission characteristics of a spark ignition engine fuelled with butanol isomer-gasoline blends

The heavy reliance on petroleum-derived fuels such as gasoline in the transportation sector is one of the major causes of environmental pollution. For this reason, there is a critical need to develop cleaner alternative fuels. Butanol is an alcohol with four different isomers that can be blended with gasoline to produce cleaner alternative fuels because of their favourable physicochemical properties compared to ethanol. This study examined the effect of butanol isomer-gasoline blends on the performance and emission characteristics of a spark ignition engine. The butanol isomers; n-butanol, sec-butanol, tert-butanol and isobutanol are mixed with pure gasoline at a volume fraction of 20 vol%, and the physicochemical properties of these blends are measured. Tests are conducted on a SI engine at full throttle condition within an engine speed range of 1000–5000 rpm. The results show that there is a significant increase in the engine torque, brake power, brake specific fuel consumption and CO₂ emissions with respect to those for pure gasoline. The butanol isomers-gasoline blends give slightly higher brake thermal efficiency and exhaust gas temperature than pure gasoline at higher engine speeds. The iBu20 blend (20 vol% of isobutanol in gasoline) gives the highest engine torque, brake power and brake thermal efficiency among all of the blends tested in this study. The isobutanol and n-butanol blend results in the lowest CO and HC emissions, respectively. In addition, all of the butanol isomer-gasoline blends yield lower NO emissions except for the isobutanol-gasoline blend.     

Thermodynamic,environmental and economic effects of diesel and biodiesel fuels on exhaust emissions and nano-particles of a diesel engine

In this study, diesel (JIS#2) and various biodiesel fuels (BDF20, BDF50, BDF100) are used to operate the diesel engine at 100 Nm, 200 Nm and full load; while the engine speed is 1800 rpm. The system is experimentally studied, and the energy, exergy, sustainability, thermoeconomic and exergoeconomic analyses are performed to the system. The Engine Exhaust Particle Sizer is used to measure the size distribution of engine exhaust particle emissions. Also, the data of the exhaust emissions, soot, particle numbers, fuel consumptions, etc. are measured. It is found that (i) most of the exhaust emissions (except NO_x) are directly proportional to the engine load, (ii) maximum CO₂ and NO_x emissions rates are generally determined for the BDF100 biodiesel fuel; while the minimum ones are calculated for the JIS#2 diesel fuel. On the other hand, the maximum CO and HC emissions rates are generally computed for the JIS#2 diesel fuel; while the minimum ones are found for the BDF100 biodiesel fuel, (iii) fuel consumptions from maximum to minimum are BDF100 > BDF50 > BDF20 > JIS#2 at all of the engine loads, (iv) particle concentration of the JIS#2 diesel fuel is higher than the biodiesel fuels, (v) soot concentrations of the JIS#2, BDF20 and BDF50 fuels are directly proportional to the engine load; while the BDF100 is inversely proportional, (vi) system has better energy and exergy efficiency when the engine is operated with the biodiesel fuels (vii) sustainability of the fuels are BDF100 > BDF50 > BDF20 > JIS#2, (viii) thermoeconomic and exergoeconomic parameters rates from maximum to minimum are JIS#2 > BDF20 > BDF50 > BDF100.     

Characteristics of gaseous and particulate pollutants exhaust from logistics transportation vehicle on real-world conditions

On-road vehicle tests of three heavy duty diesel trucks were conducted by a portable emission measurement system (PEMS) in Chengdu, China. SEMTECH-ECOSTAR provided by Sensors Inc. was employed to detect gaseous emissions and MI2, an emissions measuring instrument powered by the Pegasor Particulate Sensor (PPS) was used to detect particulate emissions during the tests. The impacts of speed, acceleration and engine load on emissions were analyzed. The average nitrogen oxides (NOx) emission factors of the heavy duty diesel truck (HDDT), medium-duty diesel truck (MDDT), light duty diesel truck (LDDT) were 7.29, 5.29 and 5.53 g/km. The particulate emission factors were 0.60, 0.30 and 0.14 g/km respectively, higher than the similar reported in the previous studies. Both gaseous and particulate emission exhibit significant correlations with the change in vehicle speed, acceleration and power demand. The highest emission was generally in high VSPs and higher loads. High engine load caused by aggressive driving was the main factor of high emissions for the vehicles on real-world conditions.     

Estimation of nitrogen oxides emissions from petrol and diesel passenger cars by means of on-board monitoring: Effect of vehicle speed,vehicle technology,engine type on emission rates

NO_X emission rates of 13 petrol and 3 diesel passenger cars as a function of average speed from 10 to 120 km/h, emission class (pre-Euro 1 – Euro 5), engine type were investigated by on-board monitoring on roads and highways of St. Petersburg using a portative Testo XXL 300 gas analyzer. The highest level of NO_X emission 0.5–2.5 g/km was inherent to old pre-Euro 1 petrol cars without a catalytic converter. NO_X emissions rates of Euro 1 and Euro 2 petrol cars changed within 0.15–0.9 g/km, Euro 3 – 0.015–0.27 g/km, Euro 4 – 0.013–0.1 g/km, Euro 5 – 0.002–0.043 g/km. Euro 3 – Euro 4 petrol cars generally satisfied corresponding NO_X Emission Standards (ES), except cold-start period, Euro 5 petrol cars did not exceed ES. Warmed, stabilized engines of Euro 3 – Euro 5 petrol cars showed 5–10 times lower NO_X emission rates than corresponding ES in the range of speed from 20 to 90 km/h. NO_X emission rates of diesel Euro 3 and Euro 4 cars varied from 0.45 to 1.1 g/km and from 0.31 to 1.1 g/km, respectively. Two examined diesel Euro 3 and one Euro 4 passenger vehicles did not satisfy NO_X ES at real use. Euro 3 diesel cars showed 28.9 times higher NO_X emissions than Euro 3 petrol cars and Euro 4 diesel car demonstrated 17.6 times higher NO_X emissions than Euro 4 petrol cars at warmed and stabilized engine at a cruise speed ranging from 30 to 60 km/h.     

Development of optimum friction new nano hybrid composite liner for biodiesel fuel engine

This work presents the preparation of aluminum (Al) 6061 nano hybrid composite samples reinforced with equal weight percentage of nano-ZrO₂, micro-SiC, micro-Gr particles of 0%, 0.75%, 1.5%, 2.25%, and 3% using stir casting method. Friction characteristics of the composite samples under reciprocating conditions were studied at 125 °C using L₂₇ orthogonal array and Taguchi method. The results of analysis of variance showed the influencing parameter for friction coefficient in the order of applied load and reciprocating sliding speed, followed by sliding distance and percent reinforcement. Hence, the total combined reinforcement sample of 6.75% was found to be optimum in terms of frictional characteristics and tensile strength. It was selected to synthesize lightweight nano hybrid composite cylinder liner (NL) and to replace the present cast iron cylinder liner (CL) used in biodiesel engine application. The developed NL had a 43.75% reduced weight than the currently used CL. Neat diesel and biodiesel from Jatropha oil and its diesel blends were used as test fuels. Experimental results proved that NL improved brake thermal efficiency, in-cylinder pressure, heat release rate and reduced carbon monoxide, hydrocarbon, and smoke emission in comparison with the existing liner. The results also showed that emission of the oxides of nitrogen (NO_x) increased marginally with the new liner. Thus, the newly developed NL was found suitable for both diesel- and biodiesel-operated internal combustion engines.     

General statistics of diesel engines’ idle time: Shunting locomotives in industrial sidings in Poland 2009…2013

Shunting locomotive/switcher (AmE)/utilization profiles are analyzed in this paper, in particular on the basis of idle time data collected in nineteen Polish industrial sidings and yards. 40 years old, diesel-electric locomotives are observed during 1000 h. Idle times related to work cycles are analyzed statistically. The percentage of the shunting locomotive daily operating time that the engine is operating at idle amounts to 70% (from 55% to 90%), and average daily idle fuels consumption amounts to 150 l a day (from 90 to 240 l a day).Many European and Asian countries still operate a significant number of similar (ChME3, e.g. S200) old, diesel-electric locomotives (almost 8000 locomotives have been produced), for moving trains over long distances and as shunting locomotives.Observed frequent short idle time periods suggest necessity of widening future scope of idling times’ analysis. Adaptation of Polish rolling stock will be possible using prior general public education about dangerous carcinogens in diesel exhaust smoke and fuel waste related to diesel engines’ idling. Simple simultaneous depiction of diesel engine power time series together with idle time could be used for educational visualization of idling among a wider audience. In the future classical aggregated idle time statistics should be supplemented by models that are more related to the variability of shunting locomotives diesel generator’s power time series, e.g. distribution of frequent short individual idle time cases.     

Isocyanic acid and ammonia in vehicle emissions

Vehicles are considered to be an important source of ammonia (NH₃) and isocyanic acid (HNCO). HNCO and NH₃ have been shown to be toxic compounds. Moreover, NH₃ is also a precursor in the formation of atmospheric secondary aerosols. For that reason, real-time vehicular emissions from a series of Euro 5 and Euro 6 light-duty vehicles, including spark ignition (gasoline and flex-fuel), compression ignition (diesel) and a plug-in electric hybrid, were investigated at 23 and −7 °C over the new World harmonized Light-duty vehicle Test Cycle (WLTC) in the Vehicle Emission Laboratory at the European Commission Joint Research Centre Ispra, Italy. The median HNCO emissions obtained for the studied fleet over the WLTC were 1.4 mg km⁻¹ at 23 °C and 6 mg km⁻¹ at −7 °C. The fleet median NH₃ emission factors were 10 mg km⁻¹ and 21 mg km⁻¹ at 23 and −7 °C, respectively. The obtained results show that even though three-way catalyst (TWC), selective catalytic reduction (SCR), and NOx storage catalyst (NSC) are effective systems to reduce NOx vehicular emissions, they also lead to considerable emissions of the byproducts NH₃ and/or HNCO. It is also shown that diesel light-duty vehicles equipped with SCR can present NH₃ emission factors as high as gasoline light-duty vehicles at both, 23 and −7 °C over the WLTC. Therefore, with the introduction in the market of this DeNOx technology, vehicular NH₃ emissions will increase further.     

Environmental effect of CI engine using microalgae methyl ester with doped nano additives

Algae are organisms that grow in marine environments and use carbon dioxide and light to create bio-mass. There are two groupings of algae: microalgae and macroalgae. Macroalgae are the large, multi-cellular algae often seen growing in ponds. Microalgae, on the other hand, are tiny, unicellular algae that normally grow in suspension within a body of water. Algae oil from microalgae has the possible to become a sustainable fuel source as biodiesel. Microalgae are produced through photosynthesis by utilizing sunlight, water, carbon dioxide and other nutrients. The Botryococcus braunii algal oil was extracted by mechanical extraction method. The transesterification reaction of Botryococcus braunii algal oil with methanol and base catalyst was used for the production of biodiesel. The samples B20 were prepared for each methyl ester obtained from Botryococcus braunii algal oil separately and then the doping of TiO₂ and SiO₂ nanoparticles were added to the each B20 blend samples at a dosage of 50 ppm and 100 ppm with an aid of ultrasonicator. Moreover, in the absence of any engine modifications, the performance and emission characteristics of those blend samples have been investigated from the experimentally measured values such as density, viscosity, calorific value, etc. while the engine performance was also analyzed through the parameters like BSFC, BTH, exhaust emission of CO, HC, NOx and CO₂. The experimental results reveal that the use of biodiesel blend with nano additives in diesel engine has exhibited good improvement in performance characteristic and reduction in exhaust emissions.     

An assessment of gasoline motorcycle emissions performance and understanding their contribution to Tehran air pollution

Motorcycles are the third most common means of transportation in the megacity of Tehran. Hence, measurements of emission factors are essential for Tehran motorcycle fleets. In this study, 60 carburetor motorcycles of various mileages and engine displacement volumes were tested in a chassis dynamometer laboratory according to cold start Euro-3 emissions certification test procedures. For almost all of the tested samples, the average carbon monoxide (CO) emission factors were about seven times higher than the limits for Euro-3 certification. No motorcycle fell within the Euro-3 certification limit on CO emissions. 125 cc engine displacement volume motorcycles, which are dominant in Tehran, have the most total unburned hydrocarbons and CO emission rates, and they have less nitrous oxides (NO_X) emission rates and fuel consumption compared to those of larger engine volume motorcycles. Calculation of fuel-based emission factors and moles of combustion products shows that about 40% of fuel consumed by 125 cc engine volume motorcycles burns to incomplete combustion products. This proportion is lower for larger engine volume motorcycles. Approximation of relative air–fuel ratio results shows very rich combustion in selected motorcycles. Using a carburetor fuel supply system, low engine compression ratio, aging, and no catalyst could be reasons for high emission rates. These reasons could possibly result in high ultrafine particles emission rates from motorcycles. Comparison of total motorcycle pollutant emissions to that of passenger cars from previous studies in Tehran shows that motorcycles contribute to pollutant much higher than their contribution to the total fleet or total travels.     

Experimental investigation of evaporation rate and exhaust emissions of diesel engine fuelled with cotton seed methyl ester and its blend with petro-diesel

An experimental study to measure the evaporation rates, engine performance and emission characteristics of cotton seed biodiesel (cotton seed oil methyl ester) and its blends in different volumetric proportions with diesel is presented. The thermo-physical properties of all the fuel blends have been measured and presented. Evaporation rates of neat cotton seed biodiesel, neat diesel and their bends have been measured under slow convective environment of air flowing with a constant temperature. Evaporation constants have been determined by using the droplet regression rate data. The neat fuels and fuel blends have been utilized in a test engine with different load conditions to evaluate the performance, combustion and emission characteristics of the fuels. The specific fuel consumption values of the two blends, viz. B25 and B75 are found to be same. At the highest load, B0 records the lowest CO volume followed by B100. From the observed evaporation, performance and emissions characteristics, it is suggested that a blend of B50 and B75 can be optimally used in standard diesel engine settings.     

Developments of CO2-emissions and costs for small electric and combustion engine vehicles in Germany

Electric vehicles have the potential to lower emissions in the mobility sector, but especially high costs might hinder their market development. This paper aims to access environmental and economic impacts and potentials by comparing CO₂-emissions and costs of small vehicles. Considering actual data it is analysed, if and under which conditions electric vehicles are financially competitive for private consumers and under which conditions emissions can be saved. For this, a multiple-stage approach is focusing on (1) emissions during production and operation, (2) private costs and (3) external costs of emissions. A model of total cost of ownership is applied for the analysis of private and external costs.Results show that emissions of electric vehicles exceed emissions of combustion engine vehicles in the production phase, but electric vehicles cause fewer emissions during operation. Total emissions can be saved by electric vehicles even with low annual driving distances (2500–5500 km/a today). Results highly depend on the form of electricity production.Today, private costs of electric vehicles exceed the costs of combustion engine vehicles. Due to cost decreases electric vehicles can gain financial advantages in the future. External costs are high, especially for combustion engine vehicles (up to 15% of private costs), but in none of the considered cases high enough to give electric vehicles a financial advantage today. This picture will change in the future.     

Technical and environmental effects of biodiesel use in local public transport

Biodiesel use in local public transport could be especially significant in improving air quality in cities. The purpose of the experiments described in this paper was to evaluate the various (10, 20 and 50%) blends of biodiesel with diesel in the context of the engine and pollution aspects. As regards the experimental use of these findings on municipal buses, these experiments were the first reference in Hungary. The ages (15–20 years) and types of buses (Ikarus-280, Ikarus-260) used in the experiments are still common vehicles in Hungarian public transport. During our measurements, there was a significant difference between the change in fuel consumption of articulated and solo buses in traffic when compared to test bench measurements. The proportion of the engine performance reduction is nearly the same as that for biodiesel share in the blends. Most pollutants were decreasing (both at idle and full rpm), but this reduction is not directly proportional to the increase of the blending percentage. However, as for CO₂, emission increase was observed in the case of idle rpm in comparison to normal diesel operation, even though this phenomenon was not due to biodiesel use, but the catalytic converter and the fact that biodiesel was used for the first time in the engine concerned.     

浅谈柴油机有害排放物生成机理及应对策略

文章通过分析柴油机主要有害排放物NOx和碳烟的形成机理,简单阐述了一些因素对排放的影响,从多方面考虑,提出降低柴油机有害排放物的有效措施。     

Preferences for alternative fuel vehicles by Dutch local governments

Using a choice model, we estimate the preferences for alternative fuel vehicles by Dutch local governments. The analysis shows that local governments are willing to pay between 25% and 50% extra for an alternative fuel vehicle without a serious loss of utility. Further, local emissions are an important criterion on which to base a decision, especially for municipalities and provinces. We also calculate the utility for a number of prominent alternative fuel vehicles. We find that show that local governments value the battery electric vehicle and biogas internal combustion engine equally. It is important, however, that the time to refuel for electric vehicles is reduced to about 30 min.     

Sulphur abatement globally in maritime shipping

In 2016, the International Maritime Organization (IMO) decided on global regulations to reduce sulphur emissions to air from maritime shipping starting 2020. The regulation implies that ships can continue to use residual fuels with a high sulphur content, such as heavy fuel oil (HFO), if they employ scrubbers to desulphurise the exhaust gases. Alternatively, they can use fuels with less than 0.5% sulphur, such as desulphurised HFO, distillates (diesel) or liquefied natural gas (LNG). The options of lighter fuels and desulphurisation entail costs, including higher energy consumption at refineries, and the present study identifies and compares compliance options as a function of ship type and operational patterns.The results indicate distillates as an attractive option for smaller vessels, while scrubbers will be an attractive option for larger vessels. For all vessels, apart from the largest fuel consumers, residual fuels desulphurised to less than 0.5% sulphur are also a competing abatement option. Moreover, we analyse the interaction between global SO_X reductions and CO₂ (and fuel consumption), and the results indicate that the higher fuel cost for distillates will motivate shippers to lower speeds, which will offset the increased CO₂ emissions at the refineries. Scrubbers, in contrast, will raise speeds and CO₂ emissions.     

Assessing CO2 emissions of electric vehicles in Germany in 2030

Electric vehicles are often said to reduce carbon dioxide (CO₂) emissions. However, the results of current comparisons with conventional vehicles are not always in favor of electric vehicles. We outline that this is not only due to the different assumptions in the time of charging and the country-specific electricity generation mix, but also due to the applied assessment method. We, therefore, discuss four assessment methods (average annual electricity mix, average time-dependent electricity mix, marginal electricity mix, and balancing zero emissions) and analyze the corresponding CO₂ emissions for Germany in 2030 using an optimizing energy system model (PERSEUS-NET-TS). Furthermore, we distinguish between an uncontrolled (i.e. direct) charging and an optimized controlled charging strategy. For Germany, the different assessment methods lead to substantial discrepancies in CO₂ emissions for 2030 ranging from no emissions to about 0.55 kg/kWh_el (110 g/km). These emissions partly exceed the emissions from internal combustion engine vehicles. Furthermore, depending on the underlying power plant portfolio and the controlling objective, controlled charging might help to reduce CO₂ emissions and relieve the electricity grid. We therefore recommend to support controlled charging, to develop consistent methodologies to address key factors affecting CO₂ emissions by electric vehicles, and to implement efficient policy instruments which guarantee emission free mobility with electric vehicles agreed upon by researchers and policy makers.     

The problem of cold starts: A closer look at mobile source emissions levels

While the phenomenon of excess vehicle emissions from cold-start conditions is well known, the magnitude and duration of this phenomenon is often unclear due to the complex chemical processes involved and uncertainty in the literature on this subject. This paper synthesizes key findings regarding the influence of ambient and engine temperatures on light-duty vehicle (LDV) emissions. Existing literature, as well as analytical tools like the U.S. Environmental Protection Agency’s Motor Vehicle Emission Simulator (MOVES), indicate that while total vehicle emissions have dropped significantly in recent years, those associated with cold starts can still constitute up to 80% for some pollutant species. Starting emissions are consistently found to make up a high proportion of total transportation-related methane (CH₄), nitrous oxide (N₂O), and volatile organic compounds (VOCs). After 3–4 min of vehicle operation, both the engine coolant and the catalytic converter have generally warmed, and emissions are significantly lower. This effect lasts roughly 45 min after the engine is shut off, though the cooling rate depends greatly on the emission species and ambient temperature. Electrically (pre-)heated catalysts, using the bigger batteries available on hybrid drivetrains and plug-in vehicles, may be the most cost-effective technology to bring down a sizable share of mobile source emissions. Trip chaining (to keep engines warm) and shifting to non-motorized modes for shorter trips, where the cold start can dominate emissions, are also valuable tactics.     

Effects of battery chemistry and performance on the life cycle greenhouse gas intensity of electric mobility

Lithium traction batteries are a key enabling technology for plug-in electric vehicles (PEVs). Traction battery manufacture contributes to vehicle production emissions, and battery performance can have significant effects on life cycle greenhouse gas (GHG) emissions for PEVs. To assess emissions from PEVs, a life cycle perspective that accounts for vehicle production and operation is needed. However, the contribution of batteries to life cycle emissions hinge on a number of factors that are largely absent from previous analyses, notably the interaction of battery chemistry alternatives and the number of electric vehicle kilometers of travel (e-VKT) delivered by a battery. We compare life cycle GHG emissions from lithium-based traction batteries for vehicles using a probabilistic approach based on 24 hypothetical vehicles modeled on the current US market. We simulate life-cycle emissions for five commercial lithium chemistries. Examining these chemistries leads to estimates of emissions from battery production of 194–494 kg CO₂ equivalent (CO₂e) per kWh of battery capacity. Combined battery production and fuel cycle emissions intensity for plug-in hybrid electric vehicles is 226–386 g CO₂e/e-VKT, and for all-electric vehicles 148–254 g CO₂e/e-VKT. This compares to emissions for vehicle operation alone of 140–244 g CO₂e/e-VKT for grid-charged electric vehicles. Emissions estimates are highly dependent on the emissions intensity of the operating grid, but other upstream factors including material production emissions, and operating conditions including battery cycle life and climate, also affect life cycle GHG performance. Overall, we find battery production is 5–15% of vehicle operation GHG emissions on an e-VKT basis.     

Analysis of fuel consumption and pollutant emissions of regulated and alternative driving cycles based on real-world measurements

Discrepancies between real-world use of vehicles and certification cycles are a known issue. This paper presents an analysis of vehicle fuel consumption and pollutant emissions of the European certification cycle (NEDC) and the proposed worldwide harmonized light vehicles test procedure (WLTP) Class 3 cycle using data collected on-road. Sixteen light duty vehicles equipped with different propulsion technologies (spark-ignition engine, compression-ignition engine, parallel hybrid and full hybrid) were monitored using a portable emission measurement system under real-world driving conditions. The on-road data obtained, combined with the Vehicle Specific Power (VSP) methodology, was used to recreate the dynamic conditions of the NEDC and WLTP Class 3 cycle. Individual vehicle certification values of fuel consumption, CO₂, HC and NO_x emissions were compared with test cycle estimates based on road measurements. The fuel consumption calculated from on-road data is, on average, 23.9% and 16.3% higher than certification values for the recreated NEDC and WLTP Class 3 cycle, respectively. Estimated HC emissions are lower in gasoline and hybrid vehicles than certification values. Diesel vehicles present higher estimated NO_x emissions compared to current certification values (322% and 326% higher for NO_x and 244% and 247% higher for HC + NO_x for NEDC and WLTP Class 3 cycle, respectively).