钙钛矿型La（0.3）Ca（0.7）FeO3的制备及其电化学性能

采用甘氨酸-硝酸盐燃烧法制备了钙钛矿型复合氧化物La0.3Ca0.7FeO3,并用X-射线衍射分析,扫描电镜,X-射线能谱仪对纳米晶体的晶型、晶粒大小、形貌及组成进行表征.用乙炔黑为载体制备功能氧电极,采用三电极体系,测试循环伏安曲线.结果表明：800℃焙烧2 h得到完整的晶体,晶体粒子大小均匀,粒径为17.9 nm,为菱形晶系;同时该氧电极具有明显的电催化特性.     

La0.7Sr0.3Co0.3Fe0.7O3纳米纤维的合成及其NO气敏特性研究

用简单有效的静电纺丝法合成了La0.7Sr0.3Co0.3Fe0.7O3纳米纤维材料,并采用X-射线衍射和扫描电子显微镜对其晶体结构和形貌进行表征.结果显示,合成纤维的直径在150～ 300nm之间,长度达到几十个微米.以钇稳氧化锆为固体电解质,合成的La0.7Sr0.3Co0.3Fe0.7O3纳米纤维材料为感测电极,...     

Na_3La_9B_8O_(27):Ln~(3+)(Ln=Eu或Tb)荧光体的制备与发光性能

采用高温固相合成技术、溶胶-凝胶法、助熔剂法制备了Na3La9B8O27：Ln^3＋（Ln=Eu或Tb）荧光体，确定了固相反应制备该荧光体适宜的组分re．g,j．分别测试、解释了Na3La9B8O27：Ln^3＋和Na3La9B8O27：Tb^3激发光谱和发射光谱．比较了不同方法制备的荧光体的发光效率，并对产生的差异进行分析和讨论，助熔剂法得到的荧光体发光效率最高．     

Hydrographic structure and zooplankton abundance and diversity off Paita, northern Peru (1994 to 2004) — ENSO effects, trends and changes

The objective of the present study was to verify possible spatial, seasonal, and inter-annual changes in the zooplankton off Paita (northern Peru), an upwelling area located closely to the limits of cold Humboldt Current and warm Equatorial Surface Waters. Zooplankton was sampled at subsurface on 53 occasions from August 1994 to December 2004 at four stations located 2 to 30 km offshore with a WP-2 net (300 µm). Extremely high surface water temperatures combined with low salinities were observed during the 1997/98 El Niño up to 29.0 °C) and in April 2002 (up to 25.0 °C). Temperatures more than 2 °C above monthly average were also observed in October 1994, in April 2000, and in November 2004. Significant trends were observed for oxygen concentration (increase) and several horizontal and vertical gradients. Among the copepods (72% of all individuals), the most abundant species were Paracalanus parvus (28%), Acartia tonsa (26%), and Calanus sp. (10%). The strong 1997–98 El Niño (EN) event led to drastic changes in species composition that were reversed during the 1998–99 La Niña (LN) event. Community parameters such as total abundance, diversity, equitability and species richness displayed marked variations associated with the 1997–98 EN and long-term trends. Long-term trends were significant for several vertical and horizontal temperature and oxygen gradients, indicating an increase in upwelling intensity at the shelf during the study period. 10-year-trends were also significant for total zooplankton abundance (increase) and community evenness (J, decline). Our data confirmed the importance of the weak EN in 2002/03 for the study region. Within the trend of increasing zooplankton abundance, a sharp step or shift was observed from 1999 to 2000. When using sequential t-tests to detect shifts in (x + 1) transformed abundance data, a significant rupture was found between the last sampling in 1999 and the first sampling in 2000. Also, a substantial decrease in diel variability occurred after 1999, probably due to changes in vertical migration patterns. The considerable increase in zooplankton abundance over the study period, the ENSO effect, and the 1999–2000 transition are discussed with regard to synchronicity with other zooplankton time series. The present study contributes with the first evidence from an important area located in the Humboldt Current for synchronous trends and changes that were previously observed elsewhere in the Pacific. Our results demonstrated the importance of long-term zooplankton monitoring studies in upwelling areas, and confirms the idea of dramatic changes in pelagic ecosystem structure occurring in the East Pacific.     

Water masses and cyclonic circulation in Bay of La Paz, Gulf of California, during June 1998

The Bay of La Paz, a coastal and shallow basin of the Gulf of California (depth<420 m), exchanges mixed-layer waters with the Gulf of California predominantly through Boca Grande (Big Mouth), in the northeastern part of the bay. Equatorial Surface Water (ESW) flows from the gulf to the bay; once there, due to evaporation processes, this water increases its salinity above 35.00, therefore becoming Gulf of California Water (GCW) Mass. During June 1998, the baroclinic circulation in the bay was dominated by a cyclonic gyre. The hydrographic dome, related to this gyre, is depicted until approximately 150-m depth. However, the vertical mixing of water between the mixed-layer and the ones below practically does not occur because of the development of a sharp pycnocline. This fact and the isolation of the bottom of the bay by a bathymetric sill (approximately 250-m depth) at Boca Grande induce low oxygen content, particularly in the bottom-waters (O₂<0.1 ml/l). Chlorophyll values are higher and with larger vertical fluctuations within the Bay of La Paz than outside.     

插入式钢圆筒筒内侧土压力分布规律及计算方法

针对插入式钢圆筒筒内土压力计算理论多样性、计算结果差别大的问题,分析筒内土压力分布规律及计算方法。结合港珠澳大桥岛隧工程西人工岛X37#钢圆筒,采用有限元软件PLAXIS 3D和多种理论计算方法对比分析筒内土压力。结果表明：筒内土压力不是随深度增加一直增大,库拉依宁法计算筒内土压力结果与三维有限元软件分析结果比较吻合,在工程设计中可以采用库拉依宁法计算筒内土压力。分析成果可以为钢圆筒筒壁水平张力计算提供依据,从而合理确定钢圆筒筒壁厚度。     

酉水大桥引桥T梁制、架和主桥悬灌同时施工的工艺研究

以湖南省张花高速酉水河大桥4 ×40 ＋80＋ 145 ＋80 m预应力混凝土连续T梁和斜高墩大跨径预应力混凝土连续梁桥桥为工程背景,引桥40mT梁和主桥18个悬臂节块同时施工,引桥40mT梁制、架先于主桥完工,根据酉水大桥4#交接墩墩身高度达57 m、直线段长度为6.5m及直线段混凝土方量为106.85 m3等特点,在架设完成的40 m T梁上布置贝雷片吊架作为施工4#交接墩边跨直线段的主要施工设备,直线段施工完成后边跨进行合龙,简述吊架构造,介绍边跨现浇段吊架施工工艺和边跨合龙张拉等关键工序,对同类桥梁加快工程施工进度和节约投资有重要指导意义.     

厄尔尼诺和拉尼娜对全球,中国气候及对航海的影响

本文用海气相互作用简述了厄尔尼诺和拉尼娜事件的成因,浅析了厄尔尼诺（ＥＬＮｉｎｏ）和拉尼娜（Ｌａ Ｎｉｎａ）事件对全球、中国气候及对航海的影响     

THE LA ANTIGEN INHIBITS THE ACTIVATION OF THE INTERFERON－INDUCIBLE PROTEIN KINASE PKR BY SEQUESTERING AND UNWINDING DOUBLE－ST

ＴＨＥＬＡＡＮＴＩＧＥＮＩＮＨＩＢＩＴＳＴＨＥＡＣＴＩＶＡＴＩＯＮＯＦＴＨＥＩＮＴＥＲＦＥＲＯＮ－ＩＮＤＵＣＩＢＬＥＰＲＯＴＥＩＮＫＩＮＡＳＥＰＫＲＢＹＳＥＱＵＥＳＴＥＲＩＮＧＡＮＤＵＮＷＩＮＤＩＮＧＤＯＵＢＬＥ－ＳＴＲＡＮＤＥＤＲＮＡＸｉａｏＱｉｕ...     

La（0.6）Sr（0.4）Co（1-y）FeyO3系阴极材料的有机凝胶法合成与电性能

采用有机凝胶法合成了中温固体氧化物燃料电池（IT-SOFCs）阴极材料La0.6Sr0.4Co1-yFeyO3（LSCF）,通过TG-DTA,XRD研究了凝胶前驱体的热分解及其相转化过程,使用直流四引线法测量了烧结体的电导率,并初步探讨了电输运机制.结果表明：凝胶前驱体在850℃焙烧2 h可以形成颗粒细小（约20 nm）、完全晶化的纳米粉体;所有LSCF烧结体的电导率随温度的升高基本上都呈先增大后减小的趋势,并在650-750℃之间达到最大值,中低温段的电导率随温度的变化符合小极化子导电机理.在相同温度下,随着Co/Fe比例的增加,LSCF烧结体的电导率增大,中低温区域内的表观活化能下降.在700℃时,La0.6Sr0.4Co1-yFeyO3陶瓷的电子电导率在195-792 S.cm^-1之间,完全能够满足IT-SOFCs的要求.