Effects of RE on the Microstructure of Mg-8Zn-4Al Magnesium Alloys

IntroductionMagnesium alloys are called green-engineeringmaterial with great development potential becauseof its low density, high specific strength and stiff-ness, superior damping capacity, good electromag-netic shielding characteristics and good machinabil-ity[1]. However, the number of commercially avail-able magnesium alloys is still limited especially forapplication at elevated temperatures. The applica-tions of most common magnesium alloys such asAZ91 and AM60 with outstanding mechani…     

Study on Damage of High Temperature Plastic Deformation for Al-Li Alloy

The security of use for Al-Li alloy will be greatly influenced by the damage degree of plastic deformation within it at high temperature . Based on continuum damage mechanics theory, the damage evolution of Al-5.44Mg-2.15Li-0.12Zr alloy during plastic deforming at high temperature is simulated by using the damage evolution model of high temperature plastic deformation. The changing rule of its inner damage with deformation temperature, strain rate and strain is gained in this paper. The equation of damage evolution for high temperature plastic deformation is developed, providing an academic basis for the technology of plastic process of Al-Li alloys.     

Improvements of elevated temperature strength and creep resistance of Mg-12Zn-4Al based alloy with calcium addition

A series of Mg-12Zn-4Al-0.3Mn (ZA124) based alloys with additions of calcium have been prepared and their microstructure and properties have been investigated. The results show that Mg-12Zn-4Al-0.3Mn alloy consists of the ??-Mg matrix and block quasicrystal and exhibits excellent creep resistance compared to commonly used AZ91 alloy. A small amount of calcium addition to the ZA124 based alloys increased the yield strenghth at both ambient and elevated temperatures as well as creep resistance, although the ductility decreased slightly. Microanalysis indicated that the addition of calcium decreased the quasicrystalline phase and caused the formation of some lamellar precipitates of Al₂Mg₅Zn₂ with orthorhombic crystal structure. This Ca-containing Al₂Mg₅Zn₂ phase with high stability straddled the grain boundaries and strengthened grain boundaries by inhibiting crack propagation during creep tests at elevated temperature.     

Coupled Thermo-Mechanical Modeling of Long Cone-Shaped Forging Based on Rigid Visco-Plastic FEM

Based on synthetically considering the coupled thermo-mechanical relations between temperature and deforming,a numerical simulation of the forging process for the special long cone-shaped workpiece of Al-5.44M-2.15L-0.12Zr alloy at high temperature was conducted by using the rigid visco-plastic finite element method.The relations between the total load and the displacement druing the forging ,and the distributions of stress,strain,temperature and strain rate,which can provide useful information for the process design,are obtained.     

Ignition-proof properties of a high-strength Mg-Gd-Ag-Zr alloy

<正>A high-strength Mg-15.3Gd-l.8Ag-0.3Zr(GQ152K,mass fraction) alloy was prepared by conventional ingot metallurgy process.The solution and aging(denoted as T6) treated alloy exhibits remarkable mechanical properties with ultimate tensile strength of 421 MPa and tensile yield strength of 309MPa.It has higher igniting temperature of 1208 K.Moreover,it can stand against flame at 1203 K for over 6 min in vertical burning tests, and its flammabiUty behavior is very similar to that of 6101A1 alloy.Vertical burning tests appear to be able to directly study the flammability behavior of Mg alloys and it appears to be a good approach to study the flammability behavior of Mg alloys in an aircraft fire accident.     

稀土元素对低温铝基钎料性能影响的研究

本文研究了稀土元素Y、Ce对Al—Zn—Cu—Si系列低温铝基钎料的熔化温度、钎焊工艺性、电极电位及其接头的机械性能、抗腐蚀性能的影响规律,结果表明:少量Y、Ce能细化晶粒,改变组织的分布状态,它们不改变钎料的电极电位,但却提高了钎焊接头的机械性能和抗腐蚀性。     

Al-27Zn合金固溶时效后硬度及耐磨性研究

研究了两种Al-27Zn合金经425℃×8h固溶及125℃时效处理后组织结构、硬度和耐磨性的变化规律.结果表明,经时效处理后合金的组织形态为：Al基体上均匀分布着少量未溶树枝状晶组织以及大量细小弥散富锌的η相;合金的硬度随着时效时间的延长先升后降,合金元素Cu、Mg的加入提高了Al-27Zn的硬度;两种合金均具有良好的耐磨性,但合金元素Cu、Mg的加入降低了耐磨性;探讨了磨损机制及材料组织、硬度对合金耐磨性的影响.     

钨合金基体相原位细观性能的测定

为研究钨合金材料基体相的细观本构关系,采用纳米压痕实验,测定了钨合金基体相微观硬度和平均弹性模量.由纳米压痕实验得到的载荷-位移关系,利用材料的弹塑性硬化模型,经有限元计算,得到了基体相细观屈服强度、硬化模量、弹塑性性能参数和应力-应变关系曲线.分析结果表明,合金成分及变形强化是影响钨合金强度和硬度的两个基本因素.钨合金基体相微观强度和硬度随变形量或钨含量增大而增大.     

5083铝合金弯曲性能的试验研究

通过实验对加工硬化和退火态两种状态下的5083铝合金板材,在室温条件下的V形弯曲性能进行了研究．试验结果表明：与加工硬化状态相比,退火态的5083强度降低,塑性有了显著的提高;相对弯曲半径愈小,5083铝合金弯曲性能愈好;随着Mg、Mn含量的增加,5083铝合金产生裂纹的倾向降低;保压时间愈长,5083铝合金弯曲回弹角度愈小．     

5083吕合金弯曲性能的试验研究

通过实验对加工硬化和退火态两种状态下的5083铝合金板材,在室温条件下的V形弯曲性能进行了研究.试验结果表明:与加工硬化状态相比,退火态的5083强度降低,塑性有了显著的提高;相对弯曲半径愈小,5083铝合金弯曲性能愈好;随着Mg、Mn含量的增加,5083铝合金产生裂纹的倾向降低;保压时间愈长,5083铝合金弯曲回弹角度愈小.     

铝与铬含量对Fe—Mn基合金电化学极化性能的影响

用测量阳极极化曲线与相应电化学参数方法研究Al与Cr含量对Fe-25Mn合金在1mol/L Na2SO4溶液中电化学极化行为的影响。在1mol/L Na2SO4溶液中,Fe-25Mn合金不能钝化。在Fe-25Mn合金中加入2．2％Al导至呈现一个广阔的活化－钝化转变区,并在高电位处显示钝化的趋势。进一步在Fe-25Mn-2.2Al合金中加入6．9％Cr则引致钝化能力显增加,并呈现窄的活化－钝化转变区及一个颇稳定的钝化区。Fe-25Mn-2.2Al-6.9Cr合金的维钝电流密度Ip接近1Cr13不锈钢的Ip值。还对加入Al或Cr和Al与Cr的优化组合提高Fe-Mn基合金钝化性能的原因进行了简单的讨论。     

复合式路面层间界面剪切滑移特性

依托南大梁高速公路复合式路面试验段, 测试了不同糙化界面的露骨率和构造深度, 并钻取芯样进行45°剪切试验。结合45°剪切试验测试结果与层间剪切过程力学特性, 将层间剪变特性曲线划分为弹性阶段、破坏阶段、剪切强度衰减阶段和残余阶段, 采用界面构造深度、剪切强度峰值、剪切强度峰值对应层间相对滑动位移和残余剪切强度等指标评价层间剪变特性, 分析了界面糙化方式、防水黏结材料类型和用量、温度和加载速率对复合式路面层间剪变特性的影响。测试结果表明: 凿毛界面构造深度(1.17mm) 大于喷砂界面构造深度(0.37mm), 结合不同糙化界面下剪切过程的层间力学特性差异, 凿毛界面较喷砂界面所成型复合试件具有更优的抗剪性能; 防水黏结材料相同时, 凿毛界面层间剪切强度峰值对应层间相对滑动位移(0.19~0.79mm) 较喷砂界面(0.16~0.33mm) 更大, 且防水黏结材料对残余剪切强度和剪切强度峰值的影响大于层间剪切强度峰值对应层间相对滑动位移的影响; 整体而言, 温度对层间剪变特性影响显著, 5℃时层间剪切强度峰值为40℃时的7.0~10.0倍, 测试条件对层间剪切强度影响较大, 50mm·min-1加载速率时测试层间剪切强度峰值为5mm·min-1加载速率时的1.9~3.5倍。可见, 凿毛糙化方式更有助于提高复合式路面层间剪切强度, 且复合式路面层间剪变特性需采用多指标予以评价。      

Wall Thinning Characteristics of Ti-3Al-2.5V Tube in Numerical Control Bending Process

A finite element(FE) model for the numerical control(NC) bending of Ti-3 Al-2.5 V titanium alloy seamless tube is established, considering the variation in the contractile strain ratio(CSR) and elastic modulus(E). The wall thinning characteristics of Ti-3 Al-2.5 V tube under different geometric and process conditions were investigated. The results showed that the CSR-E variation can change the wall thickness, but has no remarkable effect on the change characteristics. The reasonable parameter ranges are as follows: a bending-radius range not less than 1.5 times the outer diameter, a bend angle up to 180?, and a mandrel extension of 0-3 mm. The friction coefficient between the pressure die and the tube should be in the range of 0.20-0.35, and between the bending die and the tube should be in the range of 0.05-0.15. As long as the performance meets the requirements, the relative push-assistant speed should be as small as possible.     

点焊电极点焊镀锌钢板的失效分析

本文对Ｃｒ—Ｃｒ—Ｃｕ合金材料制造的电极在点焊镀锌钢板时的失效形式进行了分析．结果表明：Ｃｒ—Ｚｒ－Ｃｕ合金材料制造的电极在点焊镀锌钢板时的失效形式主要是电极头部的塑性变形、电极端面的合金化以及再结晶和粘附。点焊镀锌钢板时电极失效的主要原因是Ｃｒ—Ｚｒ—Ｃｕ名金材料的软化温度低，点焊温度下的硬度、强度低和端面的合金化。     

材料特性对转向柱碰撞性能影响的仿真研究

针对驾驶员容易在汽车正面碰撞过程中受到转向系统伤害的问题,以微型轿车的转向柱为研究对象,运用显式动力学有限元理论,建立了转向柱碰撞有限元模型;根据方向盘的碰撞要求,对材料分别为低碳钢、铝合金和高强度钢的转向柱的碰撞性能进行了研究;对比分析了转向柱的变形形态、运动位移、速度和吸能量。结果表明:铝合金和高强度钢在碰撞过程中的变形形态、变形量、碰撞时间以及吸能能力等方面均优于低碳钢,说明通过提高材料强度的方式改善转向柱的碰撞性能是可行的。研究成果为汽车转向柱的设计和碰撞性能的提高提供了依据。     

Fe-25Mn-5Al无磁与低温钢在NaOH水溶液中形成的钝化膜的XPS研究

采用Ｘ射线光电子谱仪（ＸＰＳ）研究Ｆｅ－２５Ｍｎ－５Ａｌ－０．１５Ｃ合金在３０％ＮａＯＨ溶液中钝化后形成的钝化膜。深度剖面的ＸＰＳ分析结果表明：钝化膜的最表层与主体部分分别存在结合水与由Ｆｅ２Ｏ３、Ｍｎ２Ｏ３、Ａｌ２Ｏ３、ＦｅＯ（或Ｆｅ３Ｏ４）、ＭｎＯ（或Ｍｎ３Ｏ４）及金属态Ｆｅ、Ａｌ与Ｍｎ组成的混合物。     

Calculation on the solid solution forming enthalpies of Re-Mo-Ti gradient alloy in thermodynamics

The idea about preparation of Re-Mo-Ti alloy is put forward because of applications of Re and Mo-Re alloys in aerospace. Basing on the thermodynamics theory, the feasibility of developing a new high temperature alloy Re-Mo-Ti is investigated. The solid solution forming enthalpies of binary alloys Re-Ti, Mo-Ti and Mo-Re are calculated with the Miedema thermodynamics theory. The Miedema theory of binary alloy can be used in ternary alloy through Kohler model or Toop model. The calculated results show that the forming enthalpies of binary alloys Re-Ti, Ti-Mo and Re-Mo are negative, which indicates that binary alloys Re-Ti, Ti-Mo and Re-Mo can form solid solution in wider component area. The forming enthalpies of Re-Mo-Ti ternary alloy are still negative and smaller than those of binary alloys Re-Ti, Ti-Mo or Re-Mo, which indicates it is possible to form large solid solution graph area among ternary alloys of Ti, Mo, Re elements. It is feasible to develop a new high temperature material in thermodynamics, in this material Re-Mo-Ti solid solution as base phase, and the Ti₅Re₂₄ intermetallic compounds or interphase ω (Ti₄Mo₃) as strengthening phase.     

Fe-30Mn-11Al-1C合金的调幅分解

通过金相、XRD、透射电镜和显微硬度,分析了Fe-30Mn-11A1-1C合金在450～750℃温度区间时效的组织和硬度的变化规律,研究结果表明时效温度低于450℃奥氏体难以析出第二相,其硬度变化也不大;在550～750℃时效2h,奥氏体晶内产生调幅分解,晶界析出Fe3Al,电镜可观察到典型的调幅结构,随时效温度升高调幅结构波长变大;在650℃经2h时效,有βMn析出;调幅分解及析出相都可以提高合金硬度,但析出物粗化使硬度明显降低．     

过共晶铝硅合金变质工艺研究

本文研究了P、RE、S单独加入及P-RE、P-S、P-Na联合加入对Al-20％Si合金的变质作用，比较了各自的变质效果。考察了联合变质的最佳变质温度及联合变质长效性。结果表明，P-RE、P-S联合变质具有较好的双重变质效果，联合变质后合金机械性能有较大的提高。最佳变质温度为840℃左右，变质效果至少可持续3h.     

63Sn-37Pb钎料室温单轴循环时的变形行为

在室温下通过实验研究了63Sn-37Pb钎料合金在具有不同保持时间、应变率、应变幅值、应变-时间、加载波形及加载历史下的循环变形行为.研究表明:该钎料具有明显的应变率敏感性;其单轴循环变形的瞬态行为受到保持时间、加载波形以及应变幅值的影响;该钎料合金循环变形行为的加载历史依赖性不明显.