Sources and exposure risk of trace elements for traffic policemen in roadside locations

Samples of PM_2.5 and PM₁₀ at four types of roadside location (major road, secondary road, branch road, and expressway) in Tianjin were collected and analyzed in 2015. The average annual roadside PM_2.5 and PM₁₀ concentrations were higher than the national ambient air quality standard (NAAQS: GB3095-2012). The chromium (Cr), manganese (Mn), nickel (Ni), zinc (Zn), arsenic (As), and cadmium (Cd) concentrations in both PM_2.5 and PM₁₀ over four seasons displayed significant differences (p < 0.05). An enrichment factor (EF) analysis revealed that Cd, copper (Cu), Zn, As, Ni, and Pb in PM_2.5 and PM₁₀ mainly originated from anthropogenic sources. A factor analysis (FA) and correlation analysis (CA) revealed that vehicle emissions (exhaust and non-exhaust), soil dust, coal combustion, and industrial emissions were the main sources of roadside PM_2.5 and PM₁₀ in Tianjin. Both the total hazard quotients (total HQ) and the total carcinogenic risk (total CR) for selected elements in PM_2.5 and PM₁₀ were within acceptable limits. The HQ of Pb was higher than for other metals, and it should therefore be given special attention. The CR for traffic policemen was highest for Cr exposure (1.01 × 10⁻⁵ for PM_2.5 and 1.52 × 10⁻⁵ for PM₁₀), followed by As and Ni. A sensitivity analysis showed that the total contributions of the metal concentrations, exposure time (ET), and exposure frequency (EF) accounted for over 50% of the risk for Cr, As, and Ni, suggesting that these metals had the greatest impact on the uncertainty of health risk assessments.     

Personal exposures to PM during short distance highway travel in India

Traffic is the largest contributor (37%) to urban air pollution in India. During commuting, passengers are significantly exposed to pollutants. We carried out a study on a National Highway (NH) in India to measure personal exposure to Particulate Matter (PM) in five travel modes. PM_2.5 concentrations showed the following trend: Bus > Car FA (fresh air mode of air condition) > Bus AC > Car > Car RC (re-circulation mode of air condition). Highest and lowest concentrations of PM₁₀ were observed in Bus (134 ± 47 µg m⁻³) and Car RC (20 ± 5 µg m⁻³), respectively. The exposures were highest at the rear seats during the Bus AC journeys. In Car FA, the contribution of PM₁ to total concentrations was dominant (61%). Travel modes explained highest variabilities in PM₁₀, PM_2.5 and PM₁ concentrations. In all travel modes, the highest particle counts were observed for PM_0.3–0.5. PM_>0.5–5.0 counts during Bus journeys were comparatively higher than remaining modes. Deposition doses of passengers were as high as 3.22 µg of PM₁₀ (in Bus), 0.66 µg of PM_2.5 (in Bus) and 0.06 µg of PM₁ (in Bus AC) during the ~1 h journey. Our study revealed that Car RC is the safest mode of travel, both in terms of personal exposures and PM depositions in respiratory system. The results from this study can be used to target efforts to reduce personal exposure of highway commuters.     

Preliminary investigation of PM1, PM2.5, PM10 and its metal elemental composition in tunnels at a subway station in Shanghai,China

In this study, real-time monitoring campaigns were conducted in two tunnels (Line A and Line B) at a subway station in Shanghai, including temperature, relative humidity, PM₁, PM_2.5 and PM₁₀, in order to understand the climate and PM characteristics in the transportation microenvironment. In addition, collected floor dust particles in the tunnel were analyzed by ICP for their metal elemental composition. Strong correlations occurred between all PM levels and meteorological parameters in the tunnel of Line A (with platform screen doors), in comparison with the weak correlations between such parameters in the tunnel of Line B (without platform screen doors). PM_2.5 and PM₁₀ between peak hours and off-peak hours for both lines presented significant differences (p < 0.05), respectively. Nevertheless, PM₁ showed a different pattern, with p > 0.05 for Line A and p < 0.05 for Line B, respectively. In addition, statistical results concluded that PM had an evident weekly variation for both lines. Friday was the highest day of all particulate matters in monitoring periods for both lines. Ratios of PM₁/PM₁₀ and PM_2.5/PM₁₀ were high when trains were out of service and low when trains were in service. Relative abundance of metal elements detected from floor dust particles proved that floor dust particles in tunnels might be a major source of airborne PM in the subway microenvironments, with Fe as the most abundant metal element, followed by Ca, Al, Mg, Mn, Zn, Cu, Cr, Ni, Pb and Hg.     

Commuters’ exposure to PM2.5 and CO2 in metro carriages of Shanghai metro system

Air quality inside transportation carriages has become a public concern. A comprehensive measurement campaign was conducted to examine the commuters’ exposure to PM_2.5 (d_p ⩽ 2.5 μm) and CO₂ in Shanghai metro system under different conditions. The PM_2.5 and CO₂ concentrations inside all the measured metro lines were observed at 84 ± 42 μg/m³ and 1253.1 ± 449.1 ppm, respectively. The factors that determine the in-carriage PM_2.5 and CO₂ concentrations were quantitatively investigated. The metro in-carriage PM_2.5 concentrations were significantly affected by the ventilation systems, out-carriage PM_2.5 concentrations and the passenger numbers. The largest in-carriage PM_2.5 and CO₂ concentrations were observed at 132 μg/m³ and 1855.0 ppm inside the carriages equipped with the oldest ventilation systems. The average PM_2.5 and CO₂ concentrations increased by 24.14% and 9.93% as the metro was driven from underground to overground. The average in-carriage PM_2.5 concentrations increased by 17.19% and CO₂ concentration decreased by 16.97% as the metro was driven from urban to the suburban area. It was found that PM_2.5 concentration is proportional to the on-board passenger number at a ratio of 0.4 μg/m³·passenger. A mass-balance model was developed to estimate the in-carriage PM_2.5 concentration under different driving conditions.     

Particulate matter concentrations and heavy metal contamination levels in the railway transport system of Sydney,Australia

Sampling campaign was conducted over six weeks to determine particulate matter (PM) concentrations from Sydney Trains airport line (T2) at both underground and ground levels using DustTrak. Dust samples were collected and analysed for 12 metals (Fe, Ca, Mn, Cr, Zn, Cu, Pb, Al, Co, Ni, Ba and Na) by atomic emission spectroscopy. Average underground PM₁₀ and PM_2.5 concentrations from inside the trains were 2.8 and 2.5 times greater than at ground level. Similarly, PM₁₀ and PM_2.5 concentrations on underground platforms were 2.7 and 2.5 times greater than ground level platforms. Average underground PM concentrations exceeded the national air quality standards for both PM₁₀ (50 µg/m³) and PM_2.5 (25 µg/m³). Correlation analysis showed a strong to moderate association between PM concentrations at ground level and background PM concentrations (r² from 0.952 to 0.500). The findings suggested that underground PM concentrations were less influenced by the ambient background than at ground level. The metal concentrations decreased in the order of Fe, Cr, Ca, Al, Na, Ba, Mn, Zn, Cu, Ni, Co and Pb. The pollution index (PI) and enrichment factor (EF) values were calculated to identify the levels and sources of contamination in the underground railway microenvironments. PM was remarkably rich in Fe with a mean concentration of 73.51 mg/g and EF of 61.31, followed by Ni and Cr. These results noticeably indicated a high level of metal contamination in the underground environments, with the principal contribution from track abrasion and wear processes.     

Characteristics of air pollutants at near and far field regions of a national highway located at an industrial complex

This paper presents the characterization of air quality monitored at near field region (NFR) and far field region (FFR) of a national highway located at an industrial complex. The pollutants such as PM₁₀, SO₂ and NO₂ were monitored in two campaigns (11th September to 18th October 2012 and 18th January to 17th February 2013). The 24 h average PM₁₀ concentration at NFR and FFR were found to be 86.69 ± 18.56 μg/m³; 73.16 ± 16.21 μg/m³ and 89.44 ± 18.69 μg/m³; 81.91 ± 16.42 μg/m³, respectively during first and second campaign. In both the campaigns PM₁₀, SO₂ and NO₂ concentration at NFR was higher than FFR. The chemical characterization of PM₁₀ at NFR and FFR indicated the abundance of major elements such as Na (NFR = 30% and FFR = 32%), Ca (NFR = 12% and FFR = 14%) and ions namely NO₃⁻ (NFR = 71% and FFR = 68%) and NH₃⁺ (NFR = 15% and FFR = 19%). Further, at FFR, SO₄²⁻ and NO₃⁻ were found to be 18% and 35% higher than NFR indicating the conversions of SO₂ and NO₂ concentration into secondary particles. The measured SO₂ and NO₂ concentrations were 23 and 21% lower at FFR when compared to NFR confirms the secondary formation.The CALPUFF, EPA regulatory model was set up to understand the dynamics of air pollutants at the industrial complex. The predicted PM₁₀, SO₂ and NO₂ concentrations at NFR and FFR were found to be 32.31 ± 1.56 μg/m³ and 31.35 ± 1.27 μg/m³; 0.37 ± 0.21 μg/m³ and 0.06 ± 0.04 μg/m³; 12.83 ± 6.55 μg/m³ and 4.67 ± 2.77 μg/m³, respectively. The model showed moderate predictions for PM₁₀ (R² = 0.44–0.52), SO₂ (R² = 0.41–0.51) and NO₂ (R² = 0.45–0.61) concentrations.     

Contrasting the direct use of data from traffic radars and video-cameras with traffic simulation in the estimation of road emissions and PM hotspot analysis

This study investigates the effect of traffic volume and speed data on the simulation of vehicle emissions and hotspot analysis. Data from a microwave radar and video cameras were first used directly for emission modelling. They were then used as input to a traffic simulation model whereby vehicle drive cycles were extracted to estimate emissions. To reach this objective, hourly traffic data were collected from three periods including morning peak (6–9 am), midday (11–2 pm), and afternoon peak (3–6 pm) on a weekday (June 23, 2016) along a high-volume corridor in Toronto, Canada. Traffic volumes were detected by a single radar and two video cameras operated by the Southern Ontario Centre for Atmospheric Aerosol Research. Traffic volume and composition derived from the radar had lower accuracy than the video camera data and the radar performance varied by lane exhibiting poorer performance in the remote lanes. Radar speeds collected at a single point on the corridor had higher variability than simulated traffic speeds, and average speeds were closer after model calibration. Traffic emissions of nitrogen oxides (NOx) and particulate matter (PM₁₀ and PM_2.5) were estimated using radar data as well as using simulated traffic based on various speed aggregation methods. Our results illustrate the range of emission estimates (NO_x: 4.0–27.0 g; PM₁₀: 0.3–4.8 g; PM_2.5: 0.2–1.3 g) for the corridor. The estimates based on radar speeds were at least three times lower than emissions derived from simulated vehicle trajectories. Finally, the PM₁₀ and PM_2.5 near-road concentrations derived from emissions based on simulated speeds were two or three times higher than concentrations based on emissions derived using radar data. Our findings are relevant for project-level emission inventories and PM hot-spot analysis; caution must be exercised when using raw radar data for emission modeling purposes.     

A model for evaluating the environmental and functional benefits of “innovative” roundabouts

This study looks at the singling out of a multi-parameter criterion for choosing conventional or innovative roundabout layouts, by taking functional, environmental and economic aspects into consideration. The performances of three conventional roundabouts (with different lane number at entries and through the ring), turbo-roundabouts and roundabouts with right-turn bypass lane on all the arms (flower roundabouts) have been compared in terms of vehicle delays and pollutant (carbon dioxide, nitrogen oxides, particle pollution (PM₁₀ and PM_2.5)) emissions. By means of closed-form capacity models and with the help of COPERT IV^© software, several traffic simulations have been carried out, referred to yearly peak flow values Q_max and ranging between 1300 and 3300 veh/h, starting from a typical annual traffic demand curve in urban areas. The estimation of cumulative vehicle delays and annual pollutant emissions, together with construction and maintenance costs has allowed working out overall costs for each roundabout under consideration, depending on the traffic demand. Thus, the proposed model allows finding the most cost-effective geometric solution as to overall costs for a comprehensive case record of traffic values.     

Integrated data-driven modeling to estimate PM2.5 pollution from heavy-duty truck transportation activity over metropolitan area

Based on the national emission inventory data from different countries, heavy-duty trucks are the highest on-road PM_2.5 emitters and their representation is estimated disproportionately using current modeling methods. This study expands current understanding of the impact of heavy-duty truck movement on the overall PM_2.5 pollution in urban areas through an integrated data-driven modeling methodology that could more closely represent the truck transportation activities. A detailed integrated modeling methodology is presented in the paper to estimate urban truck related PM_2.5 pollution by using a robust spatial regression-based truck activity model, the mobile source emission and Gaussian dispersion models. In this research, finely resolved spatial–temporal emissions were calculated using bottom-up approach, where hourly truck activity and detailed truck-class specific emissions rates are used as inputs. To validate the proposed methodology, the Cincinnati urban area was selected as a case study site and the proposed truck model was used with U.S. EPA’s MOVES and AERMOD models. The heavy-duty truck released PM_2.5 pollution is estimated using observed concentrations at the urban air quality monitoring stations. The monthly air quality trend estimated using our methodology matches very well with the observed trend at two different continuous monitoring stations with Spearman’s rank correlation coefficient of 0.885. Based on emission model results, it is found that 71 percent of the urban mobile-source PM_2.5 emissions are caused by trucks and also 21 percent of the urban overall ambient PM_2.5 concentrations can be attributed to trucks in Cincinnati urban area.     

Indoor air quality and passenger thermal comfort in Beijing metro transfer stations

In this study, particulate matter was investigated as the primary pollutant in the air quality of Beijing Metro transfer stations, and passenger thermal comfort during the transfer process was evaluated by using the relative warmth index (RWI). Passenger thermal comfort level is not ideal in 87% of the measured space and is slightly hot overall, with an RWI range of 0.20–0.43. Although 20% of the measured space has lower values than ASHRAE’s cooling comfort class, the thermal comfort level of most measured space is good in winter morning rush hours, with an RWI range from −0.18 to 0.28. The particulate matter (PM) concentration is related not only to the season and spatial depth but also to the transfer design of the metro station. During the morning rush period, the concentration ranges difference of PM₁₀ and PM_2.5 in winter are 262.9 μg/m³ and 125.5 μg/m³, respectively, which are 1.43 and 1.46 times higher than those of in summer. There are significant differences in the PM concentration and RWI values between the island and lateral platforms of Beijing Metro transfer stations, and the design of the lateral platform is superior to that of the island platform. Another exploratory experiment is conducted to determine if the PM concentration has a potential effect on human metabolic rate. The data in this paper provide a valuable reference for further comfort research and environmental control in metro station, and the conclusions may guide the further underground space design of metro transfer stations.     

A system based approach to develop hybrid model predicting extreme urban NOx and PM2.5 concentrations

One of the major drawbacks of conventional air quality models is their inability in accurately predicting extreme air pollutant concentrations. Hybrid modelling is one of the techniques that estimates/predicts the ‘entire range’ of the distribution of pollutant concentrations by combining the deterministic based models (capable in predicting average range) with suitable statistical (probability) distribution models (capable in predicting extreme range). This research paper describes system based approach in developing hybrid model to predict hourly averages as well as extreme percentile ranges of NO_x and PM_2.5 concentrations at two urban locations having complex traffic heterogeneity, highly variable tropical meteorology and different geographical characteristics. At one of the selected locations i.e. Delhi megacity, during winters, hybridization of AERMOD and Lognormal predicts NO_x and PM_2.5 concentrations satisfactorily with index of agreement ‘d’ values of 0.98–0.99, respectively; however, during summers, AERMOD-Log-logistic and AERMOD-Lognormal are best predicting NO_x and PM_2.5 concentrations with d values of 0.98–0.96, respectively. In another, i.e., Chennai, a coastal megacity, AERMOD-Lognormal predicts PM_2.5 concentrations satisfactorily with d values of 0.98 and 0.99 during winter and summer seasons, respectively. Further, hybrid model has also been used to evaluate regulatory compliance.     

The contribution of road traffic to particulate matter and metals in air pollution in the vicinity of an urban road

A detailed investigation was conducted to study the sources of particulate matter in the vicinity of an urban road in Žilina. To determine the amount of particulate matter (PM₁₀, PM_2.5 and PM₁) present in the ambient air, a reference gravimetric method was used. The main objective of this contribution was to identify the sources of these particles by means of statistical methods, specifically principal component analysis (PCA), factor analysis (FA), and absolute principal component scores (APCS), as well as using the presence of 17 metals in the particulate matter (Na, Mg, Al, Ca, V, Cr, Fe, Mn, Ni, Cu, Zn, As, Mo, Sb, Cd, Ba, Pb). To identify the metals in the particulate matter samples and to determine their abundances, spectroscopic methods were used, specifically inductively coupled plasma mass spectrometry (ICP-MS). Each of these metals may come from a specific source, such as the burning of fossil fuels in fossil fuel power plants; local heating of households; the burning of liquefied fossil fuels in the combustion engines of vehicles; the burning of coal and wood; non-combustion related emissions resulting from vehicular traffic; resuspension of traffic-related dust; and industry. Diesel vehicles and non-combustion emissions from road traffic have been identified as two key sources of the particulate matter. The results reveal that non-combustion emissions, which are associated with the elements Na, Fe, Mn, Ni, Zn, Mo, Sb, Cd, and Pb, are the major contributors, followed by combustion emissions from diesel vehicles, which are associated with the elements Mg, Ca, and Ba.     

Costs of air pollutants from shipping: a meta-regression analysis

ABSTRACT

This study estimated the external cost of air pollution from shipping by means of a meta-regression analysis, which has not been made before. Three pollutants, which were included in most of the primary studies, were considered: nitrogen oxides (NO_x), sulphur dioxides (SO₂) and particulate matters with a diameter of max 2.5 micrometres (PM_2.5). All primary studies included damages of health and a majority added impacts on agriculture and estimated the cost of air pollutants by transferring cost estimates from studies on costs of air emissions from transports in Europe. Different regression models and estimators were used and robust results were found of statistically significant emission elasticities of below one, i.e. total external costs increase by less than 1% when emissions increase by 1%. There was a small variation between the pollutants, with the highest elasticity for PM_2.5 and lowest for NO_x. Calculations of the marginal external cost of the pollutants showed the same pattern, with this cost being approximately six times higher for PM_2.5 than for the other pollutants. Common to all pollutants was that the marginal external cost decreases when emission increases. Another robust result was a significant increase in the cost of studies published in journals compared with other publication outlets. These findings point out some caution when transferring constant external unit cost of air pollutant from shipping, which is much applied in the literature, and the cost functions estimated in this study could thus provide a complementary transfer mechanism.     

PM2.5 and NOx from traffic: Human health impacts,external costs and policy implications from the Belgian perspective

This article employs an optimized impact pathway approach to marginal external health costs that relies on high-resolution dispersion models calibrated for Belgium and the surrounding areas. Per tonne, the MEHC_PM2.5 is found to be many times larger than MEHC_NOx, which is currently negative. Further, the impact of Belgian PM_2.5 emissions in the immediate area of generation is significantly larger than the impact on more distant areas; the opposite is true for NO_x. The MEHCs of both pollutants are predicted to increase in the coming years. Further analysis of the impacts of PM_2.5 and NO_x reveals that, on average, modern gasoline vehicles outperform their diesel counterparts as far as future emissions are concerned. This contrasts with findings for 2007, which suggested that Euro 5 diesels had fewer associated health costs because of the potential for ozone reduction offered by their NO_x emissions.     

Factors affecting public transportation,car, and motorcycle usage

This study established a hypothesis model based on the seemingly unrelated regression equations (SURE) model to investigate the relationship between public transportation, car, and motorcycle use in various townships in Taiwan and to analyse important factors that affect the usage of these modes. The SURE model was adopted because of the lack of a significant correlation between the dependent variables. The pairwise covariance analysis for any two of the three transportation modes revealed that the transportation modes could substitute for one another. Factors related to modal and demographic characteristics had different impacts on the usage of the three modes. The calculation of elasticity using different population densities and public transportation usage showed that when the ‘number of city bus routes’ was increased by 50% in areas with high population density and high public transportation usage, car usage decreased by 1.4%, which corresponds to 300,000 vehicles, and total CO₂ emissions reduced by 0.0204%. When the ‘total length of city bus routes’ was increased by 50%, the number of motorcycles used decreased by 83 million, and total CO₂ emissions reduced by 1.119%, which corresponds to 1.4 million tonnes of CO₂ emission. These findings suggest that these different factors had varying impacts on car and motorcycle usage in different areas. We therefore recommended that future transportation policies consider the varying transportation usage trends in different areas.     

Characteristics of particulate matter (PM) concentrations influenced by piston wind and train door opening in the Shanghai subway system

More than 9 million passengers take Shanghai’s subway system every work day. The system’s air quality has caused widespread concern because of the potential harm to passengers’ health. We measured the particulate matter (PM) concentrations at three kinds of typical underground platform (side-type, island-type, and stacked-type platforms) and inside the trains in Shanghai’s metro during 7 days of measurements in April and July 2015. Our results demonstrated that the patterns of air quality variation and PM concentrations were similar at the side-type and island-type platforms. We also found that the PM concentrations were higher on the platforms than inside the train and that the PM concentrations in the subway system were positively correlated with those in the ambient air. Piston wind generated by vehicle motion pushes air from the tunnel to the platform, so platform PM concentrations increase when trains approach the platform. However, the piston wind effect varies greatly between locations on the platform. In general, the effect of the piston wind is weaker at the middle of the platform than at both ends. PM concentrations inside the train increase after the doors open, during which time dirty platform air floods into the compartments. PM_1.0 and PM_2.5 were significantly correlated both inside the train and on the platforms. PM_1.0 accounted for 71.9% of PM_2.5 inside the train, which is higher than the corresponding platform values. Based on these results, we propose some practical suggestions to minimize air pollution damage to passengers and staff from the subway system.     

Health externalities of ship air pollution at port – Piraeus port case study

This paper is employing the well-known methodology of impact pathway approach to assess the external costs in human health from ship air pollution at port areas. The passenger port of Piraeus, Greece is the scenery of the study. Piraeus port is in the vicinity of the greater Athens metropolitan area where almost half of the country’s population lives. Hence, this port is the central hub of the Greek coastal passenger ship system which connects the islands of the Aegean Sea with land and is characterized by heavy ship traffic. The case study presented in this paper assesses the annual external cost in human health from air emissions produced by all passenger ships and cruise ships calling the port of Piraeus. Health cost from ships at port has been estimated at both local (Athens metropolitan area) and regional level (entire territory of Greece). Results show that higher costs occur at the local level. The dominant pollutants creating this cost are particulate matter (PM_2.5, and PM₁₀). Overall, the results indicate that the health impact of Piraeus’s passenger port emissions is not negligible; however the cost of PM₁₀ is considerably lower than the corresponded cost deriving from the land based industries of the Athens regional area for which comparison has been available.     

Merging bus routes in Hong Kong’s central business district: Analysis and models

A significant portion of the 200,000 people working in Hong Kong’s central business district (CBD) relies on buses as their primary means of transport. During peak hours, nearly a thousand double-decker buses pour into a tiny area of 150 ha. This causes traffic congestion and air pollution. Moreover, given that the flow is uni-directional (into the CBD in the morning and out of the CBD in the afternoon), the occupancy of buses in the CBD is actually low.In this paper, we propose to reduce traffic congestion and to increase bus occupancy by merging bus routes. We describe the peculiar situation of the CBD in Hong Kong and explain the necessary conditions for the possible success of merging routes. Our analysis shows that merging will lead to an overall benefit for all parties, including government, bus operators, and passengers. The actual merging decisions, which routes to merge and at what frequencies buses should run, are determined by a mathematical model. The model also shows quantitatively the benefits of merging routes and the impacts of other factors. The procedure that we follow and the model that we adopt can be applied to other CBD.     

Isocyanic acid and ammonia in vehicle emissions

Vehicles are considered to be an important source of ammonia (NH₃) and isocyanic acid (HNCO). HNCO and NH₃ have been shown to be toxic compounds. Moreover, NH₃ is also a precursor in the formation of atmospheric secondary aerosols. For that reason, real-time vehicular emissions from a series of Euro 5 and Euro 6 light-duty vehicles, including spark ignition (gasoline and flex-fuel), compression ignition (diesel) and a plug-in electric hybrid, were investigated at 23 and −7 °C over the new World harmonized Light-duty vehicle Test Cycle (WLTC) in the Vehicle Emission Laboratory at the European Commission Joint Research Centre Ispra, Italy. The median HNCO emissions obtained for the studied fleet over the WLTC were 1.4 mg km⁻¹ at 23 °C and 6 mg km⁻¹ at −7 °C. The fleet median NH₃ emission factors were 10 mg km⁻¹ and 21 mg km⁻¹ at 23 and −7 °C, respectively. The obtained results show that even though three-way catalyst (TWC), selective catalytic reduction (SCR), and NOx storage catalyst (NSC) are effective systems to reduce NOx vehicular emissions, they also lead to considerable emissions of the byproducts NH₃ and/or HNCO. It is also shown that diesel light-duty vehicles equipped with SCR can present NH₃ emission factors as high as gasoline light-duty vehicles at both, 23 and −7 °C over the WLTC. Therefore, with the introduction in the market of this DeNOx technology, vehicular NH₃ emissions will increase further.     

Long-term behavior of particulate matters at urban roadside and background locations in Seoul,Korea

The concentrations of particulate matter, PM_2.5, PM₁₀, and TSP at an urban roadside and an urban background station are analyzed. Data collected over a 10 year period are analyzed. The concentrations of the particulates measured at the urban site are systematically larger than at the background station. The mean PM values at the former also exhibit a slight fall over the decade unlike those at the background station. Overall, the particulate matters at both locations are in an intermediate range of global level, e.g., approximately two times lower than those in other Asian regions but higher than in Europe.